Nanoscopic hydrophilic/hydrophilic phase-separation well below the LCST of polyphosphoesters

Johannes Hunold; Thomas Wolf; Frederik R. Wurm; Dariush Hinderberger

doi:10.1039/C8CC09788G

Nanoscopic hydrophilic/hydrophilic phase-separation well below the LCST of polyphosphoesters

Johannes Hunold
, Thomas Wolf
, Frederik R. Wurm
, Dariush Hinderberger^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › Academic › peer-review

13 Citations (Scopus)

Abstract

The complex phase separation process of thermoresponsive polyphosphoesters (PPEs) with an identical side-group structure but different copolymer compositions is characterized by electron paramagnetic resonance (EPR) spectroscopy. In water these PPEs show LCST-type behavior, in which water-rich and slightly polymer-enriched nanoscopic regions are highly water swollen, and nanoscopic inhomogeneities with the lowest polarity contrast measured so far develop 8 °C below the macroscopic cloud point.

Original language	English
Pages (from-to)	3414-3417
Journal	Chemical communications
Volume	55
Issue number	23
DOIs	https://doi.org/10.1039/C8CC09788G
Publication status	Published - 21 Mar 2019
Externally published	Yes

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title = "Nanoscopic hydrophilic/hydrophilic phase-separation well below the LCST of polyphosphoesters",

abstract = "The complex phase separation process of thermoresponsive polyphosphoesters (PPEs) with an identical side-group structure but different copolymer compositions is characterized by electron paramagnetic resonance (EPR) spectroscopy. In water these PPEs show LCST-type behavior, in which water-rich and slightly polymer-enriched nanoscopic regions are highly water swollen, and nanoscopic inhomogeneities with the lowest polarity contrast measured so far develop 8 °C below the macroscopic cloud point.",

author = "Johannes Hunold and Thomas Wolf and Wurm, \{Frederik R.\} and Dariush Hinderberger",

year = "2019",

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doi = "10.1039/C8CC09788G",

language = "English",

volume = "55",

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journal = "Chemical communications",

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T1 - Nanoscopic hydrophilic/hydrophilic phase-separation well below the LCST of polyphosphoesters

AU - Hunold, Johannes

AU - Wolf, Thomas

AU - Wurm, Frederik R.

AU - Hinderberger, Dariush

PY - 2019/3/21

Y1 - 2019/3/21

N2 - The complex phase separation process of thermoresponsive polyphosphoesters (PPEs) with an identical side-group structure but different copolymer compositions is characterized by electron paramagnetic resonance (EPR) spectroscopy. In water these PPEs show LCST-type behavior, in which water-rich and slightly polymer-enriched nanoscopic regions are highly water swollen, and nanoscopic inhomogeneities with the lowest polarity contrast measured so far develop 8 °C below the macroscopic cloud point.

AB - The complex phase separation process of thermoresponsive polyphosphoesters (PPEs) with an identical side-group structure but different copolymer compositions is characterized by electron paramagnetic resonance (EPR) spectroscopy. In water these PPEs show LCST-type behavior, in which water-rich and slightly polymer-enriched nanoscopic regions are highly water swollen, and nanoscopic inhomogeneities with the lowest polarity contrast measured so far develop 8 °C below the macroscopic cloud point.

U2 - 10.1039/C8CC09788G

DO - 10.1039/C8CC09788G

M3 - Article

SN - 1359-7345

VL - 55

SP - 3414

EP - 3417

JO - Chemical communications

JF - Chemical communications

IS - 23

ER -

Nanoscopic hydrophilic/hydrophilic phase-separation well below the LCST of polyphosphoesters

Abstract

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