Nanostructure Based on Polymer Brushes for Efficient Heterogeneous Catalysis in Microreactors

F. Costantini, W.P. Bula, R. Salvio, Riccardo Salvio, Jurriaan Huskens, Johannes G.E. Gardeniers, David Reinhoudt, Willem Verboom

Research output: Contribution to journalArticleAcademicpeer-review

52 Citations (Scopus)

Abstract

PGMA polymer brushes are successfully grown on the inner wall of a microreactor to give a nanostructure. The oxirane groups of the brushes are used for the anchoring of a catalyst. The utility of the combination of catalyst-functionalized brushes and a microreactor is clearly demonstrated for the TBD-catalyzed Knoevenagel condensation reaction of benzaldehyde and malononitrile
Original languageUndefined
Pages (from-to)1650-1651
Number of pages2
JournalJournal of the American Chemical Society
Volume131
Issue number5
DOIs
Publication statusPublished - 2009

Keywords

  • IR-94226
  • METIS-255509

Cite this

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title = "Nanostructure Based on Polymer Brushes for Efficient Heterogeneous Catalysis in Microreactors",
abstract = "PGMA polymer brushes are successfully grown on the inner wall of a microreactor to give a nanostructure. The oxirane groups of the brushes are used for the anchoring of a catalyst. The utility of the combination of catalyst-functionalized brushes and a microreactor is clearly demonstrated for the TBD-catalyzed Knoevenagel condensation reaction of benzaldehyde and malononitrile",
keywords = "IR-94226, METIS-255509",
author = "F. Costantini and W.P. Bula and R. Salvio and Riccardo Salvio and Jurriaan Huskens and Gardeniers, {Johannes G.E.} and David Reinhoudt and Willem Verboom",
year = "2009",
doi = "10.1021/ja807616z",
language = "Undefined",
volume = "131",
pages = "1650--1651",
journal = "Journal of the American Chemical Society",
issn = "0002-7863",
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Nanostructure Based on Polymer Brushes for Efficient Heterogeneous Catalysis in Microreactors. / Costantini, F.; Bula, W.P.; Salvio, R.; Salvio, Riccardo; Huskens, Jurriaan; Gardeniers, Johannes G.E.; Reinhoudt, David; Verboom, Willem.

In: Journal of the American Chemical Society, Vol. 131, No. 5, 2009, p. 1650-1651.

Research output: Contribution to journalArticleAcademicpeer-review

TY - JOUR

T1 - Nanostructure Based on Polymer Brushes for Efficient Heterogeneous Catalysis in Microreactors

AU - Costantini, F.

AU - Bula, W.P.

AU - Salvio, R.

AU - Salvio, Riccardo

AU - Huskens, Jurriaan

AU - Gardeniers, Johannes G.E.

AU - Reinhoudt, David

AU - Verboom, Willem

PY - 2009

Y1 - 2009

N2 - PGMA polymer brushes are successfully grown on the inner wall of a microreactor to give a nanostructure. The oxirane groups of the brushes are used for the anchoring of a catalyst. The utility of the combination of catalyst-functionalized brushes and a microreactor is clearly demonstrated for the TBD-catalyzed Knoevenagel condensation reaction of benzaldehyde and malononitrile

AB - PGMA polymer brushes are successfully grown on the inner wall of a microreactor to give a nanostructure. The oxirane groups of the brushes are used for the anchoring of a catalyst. The utility of the combination of catalyst-functionalized brushes and a microreactor is clearly demonstrated for the TBD-catalyzed Knoevenagel condensation reaction of benzaldehyde and malononitrile

KW - IR-94226

KW - METIS-255509

U2 - 10.1021/ja807616z

DO - 10.1021/ja807616z

M3 - Article

VL - 131

SP - 1650

EP - 1651

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

SN - 0002-7863

IS - 5

ER -