Nanostructure Based on Polymer Brushes for Efficient Heterogeneous Catalysis in Microreactors

F. Costantini; W.P. Bula; R. Salvio; Riccardo Salvio; Jurriaan Huskens; Johannes G.E. Gardeniers; David Reinhoudt; Willem Verboom

doi:10.1021/ja807616z

Nanostructure Based on Polymer Brushes for Efficient Heterogeneous Catalysis in Microreactors

F. Costantini
, W.P. Bula
, R. Salvio
, Riccardo Salvio
, Jurriaan Huskens
, Johannes G.E. Gardeniers
, David Reinhoudt
, Willem Verboom

Research output: Contribution to journal › Article › Academic › peer-review

70 Citations (Scopus)

7 Downloads (Pure)

Abstract

PGMA polymer brushes are successfully grown on the inner wall of a microreactor to give a nanostructure. The oxirane groups of the brushes are used for the anchoring of a catalyst. The utility of the combination of catalyst-functionalized brushes and a microreactor is clearly demonstrated for the TBD-catalyzed Knoevenagel condensation reaction of benzaldehyde and malononitrile

Original language	Undefined
Pages (from-to)	1650-1651
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	131
Issue number	5
DOIs	https://doi.org/10.1021/ja807616z
Publication status	Published - 2009

Keywords

IR-94226
METIS-255509

Access to Document

10.1021/ja807616z

Cite this

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title = "Nanostructure Based on Polymer Brushes for Efficient Heterogeneous Catalysis in Microreactors",

abstract = "PGMA polymer brushes are successfully grown on the inner wall of a microreactor to give a nanostructure. The oxirane groups of the brushes are used for the anchoring of a catalyst. The utility of the combination of catalyst-functionalized brushes and a microreactor is clearly demonstrated for the TBD-catalyzed Knoevenagel condensation reaction of benzaldehyde and malononitrile",

keywords = "IR-94226, METIS-255509",

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AU - Costantini, F.

AU - Bula, W.P.

AU - Salvio, R.

AU - Salvio, Riccardo

AU - Huskens, Jurriaan

AU - Gardeniers, Johannes G.E.

AU - Reinhoudt, David

AU - Verboom, Willem

PY - 2009

Y1 - 2009

N2 - PGMA polymer brushes are successfully grown on the inner wall of a microreactor to give a nanostructure. The oxirane groups of the brushes are used for the anchoring of a catalyst. The utility of the combination of catalyst-functionalized brushes and a microreactor is clearly demonstrated for the TBD-catalyzed Knoevenagel condensation reaction of benzaldehyde and malononitrile

AB - PGMA polymer brushes are successfully grown on the inner wall of a microreactor to give a nanostructure. The oxirane groups of the brushes are used for the anchoring of a catalyst. The utility of the combination of catalyst-functionalized brushes and a microreactor is clearly demonstrated for the TBD-catalyzed Knoevenagel condensation reaction of benzaldehyde and malononitrile

KW - IR-94226

KW - METIS-255509

U2 - 10.1021/ja807616z

DO - 10.1021/ja807616z

M3 - Article

SN - 0002-7863

VL - 131

SP - 1650

EP - 1651

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

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