Ni in CNFs: Highly Active for Nitrite Hydrogenation

Roger Brunet Espinosa, Leon Lefferts

Research output: Contribution to journalArticleAcademicpeer-review

10 Citations (Scopus)

Abstract

Nickel hairy foam, consisting of carbon nanofibers (CNFs) grown on the surface of nickel foam, were synthesized and tested for nitrite hydrogenation. The results showed that nickel "hairy" foam is catalytically active in the absence of any noble metal, which is attributed to the formation of nickel particles with high carbon content during CNF growth. These C-doped nickel particles showed catalytic properties similar to those of noble metals, but were easily deactivated as a result of oxidation treatments. This deactivation is partially attributed to nickel passivation, which is reversible by reducing with H2 at room temperature in the gas or liquid phase. In addition, oxidation treatment also caused partial removal of the carbon dissolved in the nickel particles, causing irreversible deactivation. Increasing severity of the oxidation treatment induced slower reactivation via reduction, as well as lower steady-state activities after reactivation. This irreversible deactivation is attributed to the decreased concentration of dissolved carbon. Therefore, nickel "hairy" foam is a promising hydrogenation catalyst, provided it is protected against oxygen.

Original languageEnglish
Pages (from-to)5432-5440
Number of pages9
JournalACS catalysis
Volume6
Issue number8
DOIs
Publication statusPublished - 5 Aug 2016

Fingerprint

Carbon nanofibers
Nitrites
Nickel
Hydrogenation
Foams
Carbon
Precious metals
Oxidation
Passivation
Gases
Oxygen
Catalysts
Liquids

Keywords

  • "hairy" foam
  • carbon
  • carbon nanofiber
  • dissolved C
  • nickel
  • nitrite hydrogenation
  • passivation

Cite this

Brunet Espinosa, Roger ; Lefferts, Leon. / Ni in CNFs : Highly Active for Nitrite Hydrogenation. In: ACS catalysis. 2016 ; Vol. 6, No. 8. pp. 5432-5440.
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Ni in CNFs : Highly Active for Nitrite Hydrogenation. / Brunet Espinosa, Roger; Lefferts, Leon.

In: ACS catalysis, Vol. 6, No. 8, 05.08.2016, p. 5432-5440.

Research output: Contribution to journalArticleAcademicpeer-review

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T2 - Highly Active for Nitrite Hydrogenation

AU - Brunet Espinosa, Roger

AU - Lefferts, Leon

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N2 - Nickel hairy foam, consisting of carbon nanofibers (CNFs) grown on the surface of nickel foam, were synthesized and tested for nitrite hydrogenation. The results showed that nickel "hairy" foam is catalytically active in the absence of any noble metal, which is attributed to the formation of nickel particles with high carbon content during CNF growth. These C-doped nickel particles showed catalytic properties similar to those of noble metals, but were easily deactivated as a result of oxidation treatments. This deactivation is partially attributed to nickel passivation, which is reversible by reducing with H2 at room temperature in the gas or liquid phase. In addition, oxidation treatment also caused partial removal of the carbon dissolved in the nickel particles, causing irreversible deactivation. Increasing severity of the oxidation treatment induced slower reactivation via reduction, as well as lower steady-state activities after reactivation. This irreversible deactivation is attributed to the decreased concentration of dissolved carbon. Therefore, nickel "hairy" foam is a promising hydrogenation catalyst, provided it is protected against oxygen.

AB - Nickel hairy foam, consisting of carbon nanofibers (CNFs) grown on the surface of nickel foam, were synthesized and tested for nitrite hydrogenation. The results showed that nickel "hairy" foam is catalytically active in the absence of any noble metal, which is attributed to the formation of nickel particles with high carbon content during CNF growth. These C-doped nickel particles showed catalytic properties similar to those of noble metals, but were easily deactivated as a result of oxidation treatments. This deactivation is partially attributed to nickel passivation, which is reversible by reducing with H2 at room temperature in the gas or liquid phase. In addition, oxidation treatment also caused partial removal of the carbon dissolved in the nickel particles, causing irreversible deactivation. Increasing severity of the oxidation treatment induced slower reactivation via reduction, as well as lower steady-state activities after reactivation. This irreversible deactivation is attributed to the decreased concentration of dissolved carbon. Therefore, nickel "hairy" foam is a promising hydrogenation catalyst, provided it is protected against oxygen.

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