Novel routes for the synthesis of upper rim amino and methoxycarbonyl functionalized calix[4]arenes carrying other types of functional groups

P. Timmerman; Willem Verboom; David Reinhoudt; Arturo Arduini; Stefania Grandi; Anna R. Sicuri; Andrea Pochini; Rocco Ungaro

doi:10.1055/s-1994-25435

Novel routes for the synthesis of upper rim amino and methoxycarbonyl functionalized calix[4]arenes carrying other types of functional groups

P. Timmerman, Willem Verboom, David Reinhoudt, Arturo Arduini, Stefania Grandi, Anna R. Sicuri, Andrea Pochini, Rocco Ungaro

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Abstract

The selective functionalization of calix[4]arenes 1 by iodination at the upper rim in the presence of other functionalities is described. The resulting (partly) iodinated calix[4]arenes 2 are good starting materials for the preparation of both the corresponding carboxylic ester and amino derivatives 3 and 6, respectively.

Original language	Undefined
Pages (from-to)	185-189
Journal	Synthesis
Volume	1994
Issue number	2
DOIs	https://doi.org/10.1055/s-1994-25435
Publication status	Published - 1994

Keywords

METIS-106588
IR-12287

Access to Document

10.1055/s-1994-25435

8585

Cite this

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title = "Novel routes for the synthesis of upper rim amino and methoxycarbonyl functionalized calix[4]arenes carrying other types of functional groups",

abstract = "The selective functionalization of calix[4]arenes 1 by iodination at the upper rim in the presence of other functionalities is described. The resulting (partly) iodinated calix[4]arenes 2 are good starting materials for the preparation of both the corresponding carboxylic ester and amino derivatives 3 and 6, respectively.",

keywords = "METIS-106588, IR-12287",

author = "P. Timmerman and Willem Verboom and David Reinhoudt and Arturo Arduini and Stefania Grandi and Sicuri, {Anna R.} and Andrea Pochini and Rocco Ungaro",

year = "1994",

doi = "10.1055/s-1994-25435",

language = "Undefined",

volume = "1994",

pages = "185--189",

journal = "Synthesis",

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TY - JOUR

T1 - Novel routes for the synthesis of upper rim amino and methoxycarbonyl functionalized calix[4]arenes carrying other types of functional groups

AU - Timmerman, P.

AU - Verboom, Willem

AU - Reinhoudt, David

AU - Arduini, Arturo

AU - Grandi, Stefania

AU - Sicuri, Anna R.

AU - Pochini, Andrea

AU - Ungaro, Rocco

PY - 1994

Y1 - 1994

N2 - The selective functionalization of calix[4]arenes 1 by iodination at the upper rim in the presence of other functionalities is described. The resulting (partly) iodinated calix[4]arenes 2 are good starting materials for the preparation of both the corresponding carboxylic ester and amino derivatives 3 and 6, respectively.

AB - The selective functionalization of calix[4]arenes 1 by iodination at the upper rim in the presence of other functionalities is described. The resulting (partly) iodinated calix[4]arenes 2 are good starting materials for the preparation of both the corresponding carboxylic ester and amino derivatives 3 and 6, respectively.

KW - METIS-106588

KW - IR-12287

U2 - 10.1055/s-1994-25435

DO - 10.1055/s-1994-25435

M3 - Article

SN - 0039-7881

VL - 1994

SP - 185

EP - 189

JO - Synthesis

JF - Synthesis

IS - 2

ER -