TY - JOUR
T1 - Np(IV) complex with task-specific ionic liquid based on CMPO
T2 - First cyclic voltammetric study
AU - Sengupta, Arijit
AU - Murali, Mallekav S.
AU - Mohapatra, Prasanta K.
AU - Iqbal, Mudassir
AU - Huskens, Jurriaan
AU - Verboom, Willem
N1 - Publisher Copyright:
© 2015 Springer-Verlag Wien.
PY - 2015/11/1
Y1 - 2015/11/1
N2 - A cyclic voltammetric study on Np(IV) complexes with task-specific ionic liquid with 3-dodecylimidazolium cation appended with diphenylcarbamoylmethylphosphine oxide and bis(trifluoromethyl-sulfonyl)-imide anion dissolved in the room temperature ionic liquid 1-butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)-imide has been carried out. The results are compared with its molecular entity, viz., octyl(phenyl)carbamoylmethylphosphine oxide dissolved in the same diluent. The diffusion coefficient values were determined using its variation with scan rate. The standard rate constant values were also computed. The activation energy for diffusion and thermodynamic parameters for the redox reactions of the Np complexes were determined and compared.
AB - A cyclic voltammetric study on Np(IV) complexes with task-specific ionic liquid with 3-dodecylimidazolium cation appended with diphenylcarbamoylmethylphosphine oxide and bis(trifluoromethyl-sulfonyl)-imide anion dissolved in the room temperature ionic liquid 1-butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)-imide has been carried out. The results are compared with its molecular entity, viz., octyl(phenyl)carbamoylmethylphosphine oxide dissolved in the same diluent. The diffusion coefficient values were determined using its variation with scan rate. The standard rate constant values were also computed. The activation energy for diffusion and thermodynamic parameters for the redox reactions of the Np complexes were determined and compared.
KW - CMPO
KW - Cyclic voltammetry
KW - Diffusion coefficient
KW - Neptunium
KW - Task-specific ionic liquid
KW - Thermodynamic parameters
KW - 2023 OA procedure
UR - http://www.scopus.com/inward/record.url?scp=84945237730&partnerID=8YFLogxK
U2 - 10.1007/s00706-015-1467-y
DO - 10.1007/s00706-015-1467-y
M3 - Article
VL - 146
SP - 1815
EP - 1821
JO - Monatshefte für Chemie
JF - Monatshefte für Chemie
SN - 0026-9247
IS - 11
ER -