Np(IV) complex with task-specific ionic liquid based on CMPO: First cyclic voltammetric study

Arijit Sengupta; Mallekav S. Murali; Prasanta K. Mohapatra; Mudassir Iqbal; Jurriaan Huskens; Willem Verboom

doi:10.1007/s00706-015-1467-y

Np(IV) complex with task-specific ionic liquid based on CMPO: First cyclic voltammetric study

Arijit Sengupta, Mallekav S. Murali^*, Prasanta K. Mohapatra, Mudassir Iqbal, Jurriaan Huskens, Willem Verboom

^*Corresponding author for this work

Molecular Nanofabrication

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Abstract

A cyclic voltammetric study on Np(IV) complexes with task-specific ionic liquid with 3-dodecylimidazolium cation appended with diphenylcarbamoylmethylphosphine oxide and bis(trifluoromethyl-sulfonyl)-imide anion dissolved in the room temperature ionic liquid 1-butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)-imide has been carried out. The results are compared with its molecular entity, viz., octyl(phenyl)carbamoylmethylphosphine oxide dissolved in the same diluent. The diffusion coefficient values were determined using its variation with scan rate. The standard rate constant values were also computed. The activation energy for diffusion and thermodynamic parameters for the redox reactions of the Np complexes were determined and compared.

Original language	English
Pages (from-to)	1815-1821
Number of pages	7
Journal	Monatshefte für Chemie
Volume	146
Issue number	11
DOIs	https://doi.org/10.1007/s00706-015-1467-y
Publication status	Published - 1 Nov 2015

Keywords

CMPO
Cyclic voltammetry
Diffusion coefficient
Neptunium
Task-specific ionic liquid
Thermodynamic parameters
2023 OA procedure

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10.1007/s00706-015-1467-y

ArticleFinal published version, 1.03 MBLicence: Taverne

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title = "Np(IV) complex with task-specific ionic liquid based on CMPO: First cyclic voltammetric study",

abstract = "A cyclic voltammetric study on Np(IV) complexes with task-specific ionic liquid with 3-dodecylimidazolium cation appended with diphenylcarbamoylmethylphosphine oxide and bis(trifluoromethyl-sulfonyl)-imide anion dissolved in the room temperature ionic liquid 1-butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)-imide has been carried out. The results are compared with its molecular entity, viz., octyl(phenyl)carbamoylmethylphosphine oxide dissolved in the same diluent. The diffusion coefficient values were determined using its variation with scan rate. The standard rate constant values were also computed. The activation energy for diffusion and thermodynamic parameters for the redox reactions of the Np complexes were determined and compared.",

keywords = "CMPO, Cyclic voltammetry, Diffusion coefficient, Neptunium, Task-specific ionic liquid, Thermodynamic parameters, 2023 OA procedure",

author = "Arijit Sengupta and Murali, {Mallekav S.} and Mohapatra, {Prasanta K.} and Mudassir Iqbal and Jurriaan Huskens and Willem Verboom",

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doi = "10.1007/s00706-015-1467-y",

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T1 - Np(IV) complex with task-specific ionic liquid based on CMPO

T2 - First cyclic voltammetric study

AU - Sengupta, Arijit

AU - Murali, Mallekav S.

AU - Mohapatra, Prasanta K.

AU - Iqbal, Mudassir

AU - Huskens, Jurriaan

AU - Verboom, Willem

PY - 2015/11/1

Y1 - 2015/11/1

N2 - A cyclic voltammetric study on Np(IV) complexes with task-specific ionic liquid with 3-dodecylimidazolium cation appended with diphenylcarbamoylmethylphosphine oxide and bis(trifluoromethyl-sulfonyl)-imide anion dissolved in the room temperature ionic liquid 1-butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)-imide has been carried out. The results are compared with its molecular entity, viz., octyl(phenyl)carbamoylmethylphosphine oxide dissolved in the same diluent. The diffusion coefficient values were determined using its variation with scan rate. The standard rate constant values were also computed. The activation energy for diffusion and thermodynamic parameters for the redox reactions of the Np complexes were determined and compared.

AB - A cyclic voltammetric study on Np(IV) complexes with task-specific ionic liquid with 3-dodecylimidazolium cation appended with diphenylcarbamoylmethylphosphine oxide and bis(trifluoromethyl-sulfonyl)-imide anion dissolved in the room temperature ionic liquid 1-butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)-imide has been carried out. The results are compared with its molecular entity, viz., octyl(phenyl)carbamoylmethylphosphine oxide dissolved in the same diluent. The diffusion coefficient values were determined using its variation with scan rate. The standard rate constant values were also computed. The activation energy for diffusion and thermodynamic parameters for the redox reactions of the Np complexes were determined and compared.

KW - CMPO

KW - Cyclic voltammetry

KW - Diffusion coefficient

KW - Neptunium

KW - Task-specific ionic liquid

KW - Thermodynamic parameters

KW - 2023 OA procedure

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U2 - 10.1007/s00706-015-1467-y

DO - 10.1007/s00706-015-1467-y

M3 - Article

SN - 0026-9247

VL - 146

SP - 1815

EP - 1821

JO - Monatshefte für Chemie

JF - Monatshefte für Chemie

IS - 11

ER -

Np(IV) complex with task-specific ionic liquid based on CMPO: First cyclic voltammetric study

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Keywords

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