Nuclear quadrupolar spin relaxation and association in binary liquid metallic alloys

M. Elwenspoek, R. Brinkmann, P. Maxim, C. Paulick, D. Quitmann

    Research output: Contribution to journalArticleAcademic

    5 Citations (Scopus)
    79 Downloads (Pure)

    Abstract

    We present experimental data for the nuclear quadrupolar spin relaxation rate Rq in liquid InxSb1–x, HgxK1–x and In50Hg50. The results for the concentration and temperature dependence of Rq can be qualitatively interpreted with the framework of association in these systems (quasi ternary solution model). We conclude that the relaxation is mostly due to the decay of associates in HgIn and to rotational diffusion of associates in Hg – K. In In – Sb, the corresponding correlation times seem to be equal so that both relaxation processes may contribute to the relaxation. The analysis of microscopic experiments using the concept of association may prove useful for a better understanding of the nature of the associates.
    Original languageEnglish
    Pages (from-to)823-826
    JournalBerichte der Bunsen-Gesellschaft für Physikalische Chemie
    Volume87
    Issue number9
    DOIs
    Publication statusPublished - 1983

    Keywords

    • Kernquadrupolrelaxation
    • Diffusion
    • Metalle
    • Flüssigkeiten
    • Thermodynamik

    Fingerprint

    Dive into the research topics of 'Nuclear quadrupolar spin relaxation and association in binary liquid metallic alloys'. Together they form a unique fingerprint.

    Cite this