On electrolytic bubbles

Peter  van der Linde

doi:10.3990/1.9789036547413

On electrolytic bubbles

Peter van der Linde

Mesoscale Chemical Systems

Research output: Thesis › PhD Thesis - Research UT, graduation UT

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Abstract

A better understanding of electrolysis-driven bubble evolution stages is provided: namely the nucleation, growth, and detachment. Superhydrophobic cavities were used to predefine the onset location of electrolytic bubbles on substrates. Using single and multiple superhydrophobic cavities on substrates allowed the elucidation of dissolved gas boundary layer phenomena associated to bubble evolution and the electric potential response caused by detaching electrolytic bubbles in the electrolysis of water. The complex bubble evolution during the electrolysis of water has been compared in experimental and theoretical work with the well-understood evolution of CO2 bubbles in pressure driven supersaturation.

Original language	English
Qualification	Doctor of Philosophy
Awarding Institution	University of Twente
Supervisors/Advisors	Gardeniers, J.G.E., Supervisor Fernández Rivas , David, Co-Supervisor
Award date	4 Apr 2019
Place of Publication	Enschede
Publisher	University of Twente
Print ISBNs	978-90-365-4741-3
DOIs	https://doi.org/10.3990/1.9789036547413
Publication status	Published - 4 Apr 2019

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10.3990/1.9789036547413

Thesis P. van der LindeFinal published version, 22.2 MB

Influence of Bubbles on the Energy Conversion Efficiency of Electrochemical Reactors
Angulo, A., van der Linde, P., Gardeniers, H., Modestino, M. A. & Fernandez Rivas, D., 18 Mar 2020, In: Joule. 4, 3, p. 555-579 25 p.
Research output: Contribution to journal › Review article › Academic › peer-review

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title = "On electrolytic bubbles",

abstract = "A better understanding of electrolysis-driven bubble evolution stages is provided: namely the nucleation, growth, and detachment. Superhydrophobic cavities were used to predefine the onset location of electrolytic bubbles on substrates. Using single and multiple superhydrophobic cavities on substrates allowed the elucidation of dissolved gas boundary layer phenomena associated to bubble evolution and the electric potential response caused by detaching electrolytic bubbles in the electrolysis of water. The complex bubble evolution during the electrolysis of water has been compared in experimental and theoretical work with the well-understood evolution of CO2 bubbles in pressure driven supersaturation.",

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AB - A better understanding of electrolysis-driven bubble evolution stages is provided: namely the nucleation, growth, and detachment. Superhydrophobic cavities were used to predefine the onset location of electrolytic bubbles on substrates. Using single and multiple superhydrophobic cavities on substrates allowed the elucidation of dissolved gas boundary layer phenomena associated to bubble evolution and the electric potential response caused by detaching electrolytic bubbles in the electrolysis of water. The complex bubble evolution during the electrolysis of water has been compared in experimental and theoretical work with the well-understood evolution of CO2 bubbles in pressure driven supersaturation.

U2 - 10.3990/1.9789036547413

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M3 - PhD Thesis - Research UT, graduation UT

SN - 978-90-365-4741-3

PB - University of Twente

CY - Enschede

ER -

On electrolytic bubbles

Abstract

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Research output

Influence of Bubbles on the Energy Conversion Efficiency of Electrochemical Reactors

Cite this