On the Formation of a Conducting Surface Channel by Ionic-Liquid Gating of an Insulator

Hasan Atesci, Francesco Coneri, Maarten Leeuwenhoek, Jouri Bommer, James R.T. Seddon, Hans Hilgenkamp, Jan M. Van Ruitenbeek* (Corresponding Author)

*Corresponding author for this work

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Abstract

Ionic-liquid gating has become a popular tool for tuning the charge carrier densities of complex oxides. Among these, the band insulator SrTiO3 is one of the most extensively studied materials. While experiments have succeeded in inducing (super)conductivity, the process by which ionic-liquid gating turns this insulator into a conductor is still under scrutiny. Recent experiments have suggested an electrochemical rather than electrostatic origin of the induced charge carriers. Here, experiments probing the time evolution of conduction of SrTiO3 near the glass transition temperature of the ionic liquid are reported. By cooling down to temperatures near the glass transition of the ionic liquid, the process develops slowly and can be seen to evolve in time. The experiments reveal a process characterized by waiting times that can be as long as several minutes preceding a sudden appearance of conduction. For the conditions applied in our experiments, a consistent interpretation in terms of an electrostatic mechanism for the formation of a conducting path at the surface of SrTiO3 is found. The mechanism by which the conducting surface channel develops relies on a nearly homogeneous lowering of the surface potential until the conduction band edge of SrTiO3 reaches the Fermi level of the electrodes.

Original languageEnglish
Article number1700449
Number of pages8
JournalAnnalen der Physik
Volume530
Issue number10
Early online date22 Aug 2018
DOIs
Publication statusPublished - 1 Oct 2018

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insulators
conduction
liquids
charge carriers
electrostatics
glass transition temperature
conduction bands
conductors
tuning
cooling
conductivity
electrodes
oxides
glass
temperature

Keywords

  • UT-Hybrid-D
  • ionic liquids
  • nanoionics
  • SrTiO
  • two-dimensional conductors
  • electric double layer

Cite this

Atesci, H., Coneri, F., Leeuwenhoek, M., Bommer, J., Seddon, J. R. T., Hilgenkamp, H., & Van Ruitenbeek, J. M. (2018). On the Formation of a Conducting Surface Channel by Ionic-Liquid Gating of an Insulator. Annalen der Physik, 530(10), [1700449]. https://doi.org/10.1002/andp.201700449
Atesci, Hasan ; Coneri, Francesco ; Leeuwenhoek, Maarten ; Bommer, Jouri ; Seddon, James R.T. ; Hilgenkamp, Hans ; Van Ruitenbeek, Jan M. / On the Formation of a Conducting Surface Channel by Ionic-Liquid Gating of an Insulator. In: Annalen der Physik. 2018 ; Vol. 530, No. 10.
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Atesci, H, Coneri, F, Leeuwenhoek, M, Bommer, J, Seddon, JRT, Hilgenkamp, H & Van Ruitenbeek, JM 2018, 'On the Formation of a Conducting Surface Channel by Ionic-Liquid Gating of an Insulator', Annalen der Physik, vol. 530, no. 10, 1700449. https://doi.org/10.1002/andp.201700449

On the Formation of a Conducting Surface Channel by Ionic-Liquid Gating of an Insulator. / Atesci, Hasan; Coneri, Francesco; Leeuwenhoek, Maarten; Bommer, Jouri; Seddon, James R.T.; Hilgenkamp, Hans; Van Ruitenbeek, Jan M. (Corresponding Author).

In: Annalen der Physik, Vol. 530, No. 10, 1700449, 01.10.2018.

Research output: Contribution to journalArticleAcademicpeer-review

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