Optical fiber-based-o-line UV/V is spectroscopic monitoring of chemical reaction kinetics under high pressure in a capillary microreactor

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Abstract

With a miniaturized (3 µL volume) fiber-optics based system for on-line measurement by UV/Vis spectroscopy, the reaction rate constants (at different pressures) and the activation volumes (V) were determinined for a nucleophilic aromatic substitution and an aza Diels–Alder reaction in a capillary microreactor.
Original languageUndefined
Pages (from-to)2857-2859
Number of pages3
JournalChemical communications
Volume2005
Issue number22
DOIs
Publication statusPublished - 2005

Keywords

  • IR-53001
  • METIS-225084
  • EWI-19275

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