Optical fiber-based-o-line UV/V is spectroscopic monitoring of chemical reaction kinetics under high pressure in a capillary microreactor

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Abstract

With a miniaturized (3 µL volume) fiber-optics based system for on-line measurement by UV/Vis spectroscopy, the reaction rate constants (at different pressures) and the activation volumes (V) were determinined for a nucleophilic aromatic substitution and an aza Diels–Alder reaction in a capillary microreactor.
Original languageUndefined
Pages (from-to)2857-2859
Number of pages3
JournalChemical communications
Volume2005
Issue number22
DOIs
Publication statusPublished - 2005

Keywords

  • IR-53001
  • METIS-225084
  • EWI-19275

Cite this

@article{74ee71e357c940b8a0653e45b134d2a4,
title = "Optical fiber-based-o-line UV/V is spectroscopic monitoring of chemical reaction kinetics under high pressure in a capillary microreactor",
abstract = "With a miniaturized (3 µL volume) fiber-optics based system for on-line measurement by UV/Vis spectroscopy, the reaction rate constants (at different pressures) and the activation volumes (V) were determinined for a nucleophilic aromatic substitution and an aza Diels–Alder reaction in a capillary microreactor.",
keywords = "IR-53001, METIS-225084, EWI-19275",
author = "F. Benito-Lopez and Willem Verboom and M. Kakuta and Gardeniers, {Johannes G.E.} and Egberink, {Richard J.M.} and R.E. Oosterbroek and {van den Berg}, Albert and David Reinhoudt",
note = "This research is supported by the Technology Foundation STW, applied science division of NWO and the technology program of the Ministry of Economic Affairs",
year = "2005",
doi = "10.1039/b500429b",
language = "Undefined",
volume = "2005",
pages = "2857--2859",
journal = "Chemical communications",
issn = "1359-7345",
publisher = "Royal Society of Chemistry",
number = "22",

}

TY - JOUR

T1 - Optical fiber-based-o-line UV/V is spectroscopic monitoring of chemical reaction kinetics under high pressure in a capillary microreactor

AU - Benito-Lopez, F.

AU - Verboom, Willem

AU - Kakuta, M.

AU - Gardeniers, Johannes G.E.

AU - Egberink, Richard J.M.

AU - Oosterbroek, R.E.

AU - van den Berg, Albert

AU - Reinhoudt, David

N1 - This research is supported by the Technology Foundation STW, applied science division of NWO and the technology program of the Ministry of Economic Affairs

PY - 2005

Y1 - 2005

N2 - With a miniaturized (3 µL volume) fiber-optics based system for on-line measurement by UV/Vis spectroscopy, the reaction rate constants (at different pressures) and the activation volumes (V) were determinined for a nucleophilic aromatic substitution and an aza Diels–Alder reaction in a capillary microreactor.

AB - With a miniaturized (3 µL volume) fiber-optics based system for on-line measurement by UV/Vis spectroscopy, the reaction rate constants (at different pressures) and the activation volumes (V) were determinined for a nucleophilic aromatic substitution and an aza Diels–Alder reaction in a capillary microreactor.

KW - IR-53001

KW - METIS-225084

KW - EWI-19275

U2 - 10.1039/b500429b

DO - 10.1039/b500429b

M3 - Article

VL - 2005

SP - 2857

EP - 2859

JO - Chemical communications

JF - Chemical communications

SN - 1359-7345

IS - 22

ER -