Optical spectroscopic study of Al2O3:Ti3+ under hydrostatic pressure

S. García-Revilla; F. Rodríguez; I. Hernández; R. Valiente; Markus Pollnau

doi:10.1080/08957950211372

Optical spectroscopic study of Al₂O₃:Ti³⁺ under hydrostatic pressure

S. García-Revilla, F. Rodríguez, I. Hernández, R. Valiente, Markus Pollnau

Research output: Contribution to journal › Article › Academic › peer-review

1 Citation (Scopus)

Abstract

This work investigates the effect of hydrostatic pressure on the excitation, emission and lifetime of Ti3+-doped Al2O3 in the 0–110 kbar range. The application of pressure induces band shifts that are correlated with the corresponding local structural changes undergone by the TiO6 complex. The increase of the Stokes-shift and the reduction of the Jahn–Teller (JT) splittings under pressure are analysed in terms of a simple model based on linear electron–phonon couplings to the a1g and the JT eg vibrational modes.

Original language	English
Pages (from-to)	127-130
Number of pages	4
Journal	High pressure research
Volume	22
Issue number	1
DOIs	https://doi.org/10.1080/08957950211372
Publication status	Published - 2002

Keywords

IOMS-APD: Active Photonic Devices
Optical spectroscopy
EWI-17550
IR-70084
Hydrostatic pressure
Jahn–Teller Effect
Al2O3:Ti3+

Access to Document

10.1080/08957950211372

Cite this

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title = "Optical spectroscopic study of Al2O3:Ti3+ under hydrostatic pressure",

abstract = "This work investigates the effect of hydrostatic pressure on the excitation, emission and lifetime of Ti3+-doped Al2O3 in the 0–110 kbar range. The application of pressure induces band shifts that are correlated with the corresponding local structural changes undergone by the TiO6 complex. The increase of the Stokes-shift and the reduction of the Jahn–Teller (JT) splittings under pressure are analysed in terms of a simple model based on linear electron–phonon couplings to the a1g and the JT eg vibrational modes.",

keywords = "IOMS-APD: Active Photonic Devices, Optical spectroscopy, EWI-17550, IR-70084, Hydrostatic pressure, Jahn–Teller Effect, Al2O3:Ti3+",

author = "S. Garc{\'i}a-Revilla and F. Rodr{\'i}guez and I. Hern{\'a}ndez and R. Valiente and Markus Pollnau",

year = "2002",

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journal = "High pressure research",

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T1 - Optical spectroscopic study of Al2O3:Ti3+ under hydrostatic pressure

AU - García-Revilla, S.

AU - Rodríguez, F.

AU - Hernández, I.

AU - Valiente, R.

AU - Pollnau, Markus

PY - 2002

Y1 - 2002

N2 - This work investigates the effect of hydrostatic pressure on the excitation, emission and lifetime of Ti3+-doped Al2O3 in the 0–110 kbar range. The application of pressure induces band shifts that are correlated with the corresponding local structural changes undergone by the TiO6 complex. The increase of the Stokes-shift and the reduction of the Jahn–Teller (JT) splittings under pressure are analysed in terms of a simple model based on linear electron–phonon couplings to the a1g and the JT eg vibrational modes.

AB - This work investigates the effect of hydrostatic pressure on the excitation, emission and lifetime of Ti3+-doped Al2O3 in the 0–110 kbar range. The application of pressure induces band shifts that are correlated with the corresponding local structural changes undergone by the TiO6 complex. The increase of the Stokes-shift and the reduction of the Jahn–Teller (JT) splittings under pressure are analysed in terms of a simple model based on linear electron–phonon couplings to the a1g and the JT eg vibrational modes.

KW - IOMS-APD: Active Photonic Devices

KW - Optical spectroscopy

KW - EWI-17550

KW - IR-70084

KW - Hydrostatic pressure

KW - Jahn–Teller Effect

KW - Al2O3:Ti3+

U2 - 10.1080/08957950211372

DO - 10.1080/08957950211372

M3 - Article

SN - 0895-7959

VL - 22

SP - 127

EP - 130

JO - High pressure research

JF - High pressure research

IS - 1

ER -