Order and thermochromism of poly(di-n-alkylsilane)'s

Holger Frey; Martin Möller; Krzysztof Matyjaszewski

doi:10.1016/0379-6779(91)91901-L

Order and thermochromism of poly(di-n-alkylsilane)'s

Holger Frey, Martin Möller, Krzysztof Matyjaszewski

Materials Science and Technology of Polymers

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Abstract

A series of poly(di-n-alkyl)silane copolymers derived from Poly(di-n-hexyl)silane, PDHS, was prepared. Mesomorphic phase transitions of these copolymers depend on fraction as well as on the size of the comonomers. DSC and temperature dependent UV-spectroscopy were employed to study the effect of constitutional disorder on the length of all-trans σ-conjugated Si---Si catenated chromophores.

Original language	English
Pages (from-to)	1551-1554
Number of pages	4
Journal	Synthetic metals
Volume	42
Issue number	1-2
DOIs	https://doi.org/10.1016/0379-6779(91)91901-L
Publication status	Published - 1991

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title = "Order and thermochromism of poly(di-n-alkylsilane)'s",

abstract = "A series of poly(di-n-alkyl)silane copolymers derived from Poly(di-n-hexyl)silane, PDHS, was prepared. Mesomorphic phase transitions of these copolymers depend on fraction as well as on the size of the comonomers. DSC and temperature dependent UV-spectroscopy were employed to study the effect of constitutional disorder on the length of all-trans σ-conjugated Si---Si catenated chromophores.",

author = "Holger Frey and Martin M{\"o}ller and Krzysztof Matyjaszewski",

year = "1991",

doi = "10.1016/0379-6779(91)91901-L",

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T1 - Order and thermochromism of poly(di-n-alkylsilane)'s

AU - Frey, Holger

AU - Möller, Martin

AU - Matyjaszewski, Krzysztof

PY - 1991

Y1 - 1991

N2 - A series of poly(di-n-alkyl)silane copolymers derived from Poly(di-n-hexyl)silane, PDHS, was prepared. Mesomorphic phase transitions of these copolymers depend on fraction as well as on the size of the comonomers. DSC and temperature dependent UV-spectroscopy were employed to study the effect of constitutional disorder on the length of all-trans σ-conjugated Si---Si catenated chromophores.

AB - A series of poly(di-n-alkyl)silane copolymers derived from Poly(di-n-hexyl)silane, PDHS, was prepared. Mesomorphic phase transitions of these copolymers depend on fraction as well as on the size of the comonomers. DSC and temperature dependent UV-spectroscopy were employed to study the effect of constitutional disorder on the length of all-trans σ-conjugated Si---Si catenated chromophores.

U2 - 10.1016/0379-6779(91)91901-L

DO - 10.1016/0379-6779(91)91901-L

M3 - Article

SN - 0379-6779

VL - 42

SP - 1551

EP - 1554

JO - Synthetic metals

JF - Synthetic metals

IS - 1-2

ER -

Order and thermochromism of poly(di-n-alkylsilane)'s

Abstract

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