Order-disorder reactions in the ferroelectric perovskites Pb(Sc1/2Nb1/2)O3 and Pb(Sc1/2Ta1/2)O3: II. Relation between ordering and properties

C.G.F. Stenger; A.J. Burggraaf

doi:10.1002/pssa.2210610240

Order-disorder reactions in the ferroelectric perovskites Pb(Sc_1/2Nb_1/2)O₃ and Pb(Sc_1/2Ta_1/2)O₃: II. Relation between ordering and properties

C.G.F. Stenger, A.J. Burggraaf

Inorganic Materials Science

Research output: Contribution to journal › Article › Academic

198 Citations (Scopus)

170 Downloads (Pure)

Abstract

The ordering of the trivalent and pentavalent cations in the perovskites Pb(Sc1/2Nb1/2)O3 and Pb(Sc1/2Ta1/2)O3 can be varied by suitable heat treatments. The degree as well as the kind of order strongly affects the character of the FE - PE phase transition. A spatially homogeneous disorder leads to a diffuse phase transition whereas a hybrid crystal with a nonhomogeneous disorder shows a sequence of two FE - PE transitions.

Original language	English
Pages (from-to)	653-664
Journal	Physica Status Solidi A: Applied research
Volume	61
Issue number	2
DOIs	https://doi.org/10.1002/pssa.2210610240
Publication status	Published - 1980

Access to Document

10.1002/pssa.2210610240

Stenger80order2Final published version, 807 KB

Cite this

@article{9f147fcf3cc94d01a307e21f684c55c6,

title = "Order-disorder reactions in the ferroelectric perovskites Pb(Sc1/2Nb1/2)O3 and Pb(Sc1/2Ta1/2)O3: II. Relation between ordering and properties",

abstract = "The ordering of the trivalent and pentavalent cations in the perovskites Pb(Sc1/2Nb1/2)O3 and Pb(Sc1/2Ta1/2)O3 can be varied by suitable heat treatments. The degree as well as the kind of order strongly affects the character of the FE - PE phase transition. A spatially homogeneous disorder leads to a diffuse phase transition whereas a hybrid crystal with a nonhomogeneous disorder shows a sequence of two FE - PE transitions.",

author = "C.G.F. Stenger and A.J. Burggraaf",

year = "1980",

doi = "10.1002/pssa.2210610240",

language = "English",

volume = "61",

pages = "653--664",

journal = "Physica Status Solidi A: Applied research",

issn = "0031-8965",

publisher = "Wiley-VCH Verlag",

number = "2",

}

TY - JOUR

T1 - Order-disorder reactions in the ferroelectric perovskites Pb(Sc1/2Nb1/2)O3 and Pb(Sc1/2Ta1/2)O3

T2 - II. Relation between ordering and properties

AU - Stenger, C.G.F.

AU - Burggraaf, A.J.

PY - 1980

Y1 - 1980

N2 - The ordering of the trivalent and pentavalent cations in the perovskites Pb(Sc1/2Nb1/2)O3 and Pb(Sc1/2Ta1/2)O3 can be varied by suitable heat treatments. The degree as well as the kind of order strongly affects the character of the FE - PE phase transition. A spatially homogeneous disorder leads to a diffuse phase transition whereas a hybrid crystal with a nonhomogeneous disorder shows a sequence of two FE - PE transitions.

AB - The ordering of the trivalent and pentavalent cations in the perovskites Pb(Sc1/2Nb1/2)O3 and Pb(Sc1/2Ta1/2)O3 can be varied by suitable heat treatments. The degree as well as the kind of order strongly affects the character of the FE - PE phase transition. A spatially homogeneous disorder leads to a diffuse phase transition whereas a hybrid crystal with a nonhomogeneous disorder shows a sequence of two FE - PE transitions.

U2 - 10.1002/pssa.2210610240

DO - 10.1002/pssa.2210610240

M3 - Article

SN - 0031-8965

VL - 61

SP - 653

EP - 664

JO - Physica Status Solidi A: Applied research

JF - Physica Status Solidi A: Applied research

IS - 2

ER -

Order-disorder reactions in the ferroelectric perovskites Pb(Sc1/2Nb1/2)O3 and Pb(Sc1/2Ta1/2)O3: II. Relation between ordering and properties

Abstract

Access to Document

Fingerprint

Cite this

Order-disorder reactions in the ferroelectric perovskites Pb(Sc_1/2Nb_1/2)O₃ and Pb(Sc_1/2Ta_1/2)O₃: II. Relation between ordering and properties