Oxygen transport through dense perovskite-type La1-xSrxFeO3-δ membranes

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Abstract

Oxygen permeation measurements were performed on dense La1-xSrxFeO3-δ
(r=0.1-0.4) membranes at 1273 K. The materials were investigated in air/He and air/He,CO,CO2 gradients. The fluxes increased with increasing Sr content and were strongly enhanced by the presence of CO, up to values of 25 mmol m-2 s-1. In air/He gradients the permeation is bulk controlled and can be modelled by Wagner theory incorporating a random point defect model. Oxygen vacancy diffusion coefficients were calculated to range between 5.6-8.6-10-6 cm2 s-1. In air/CO,CO2 gradients the permeation process appeared to be totally limited by the surface reaction rate. To account for this behaviour, models are proposed in which surface oxygen vacancies act as active surface sites.
Original languageEnglish
Title of host publicationCeramic Membranes I
Subtitle of host publicationProceedings of the First International Symposium on Ceramic Membranes
EditorsH.U. Anderson, A.C. Khandkar, M. Liu
Place of PublicationPennington, NJ
PublisherThe Electrochemical Society Inc.
Pages37-47
Number of pages10
ISBN (Print)9781566771191
Publication statusPublished - 28 Jan 1997
Event1st International Symposium on Ceramic Membranes 1995 - Chicago, United States
Duration: 8 Oct 199513 Oct 1995
Conference number: 1

Publication series

NameProceedings
PublisherThe Electrochemical Society Inc.
Volume95-24
ISSN (Print)0161-6374

Conference

Conference1st International Symposium on Ceramic Membranes 1995
CountryUnited States
CityChicago
Period8/10/9513/10/95

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    ten Elshof, J. E., Bouwmeester, H. J. M., & Verweij, H. (1997). Oxygen transport through dense perovskite-type La1-xSrxFeO3-δ membranes. In H. U. Anderson, A. C. Khandkar, & M. Liu (Eds.), Ceramic Membranes I: Proceedings of the First International Symposium on Ceramic Membranes (pp. 37-47). (Proceedings; Vol. 95-24). Pennington, NJ: The Electrochemical Society Inc..