Passive Sampling of Airborne Peroxyacetic Acid

H. Henneken; Laura Assink; Joyce de Wit; M. Vogel; U. Karst

doi:10.1021/ac060668h

Passive Sampling of Airborne Peroxyacetic Acid

H. Henneken, Laura Assink, Joyce de Wit, M. Vogel, U. Karst

Faculty of Science and Technology

Research output: Contribution to journal › Article › Academic

11 Citations (Scopus)

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Abstract

The first passive sampling device for the determination of airborne peroxyacetic acid (PAA) is presented. 2-([3-{2-[4-Amino-2-(methylsulfanyl)phenyl]-1-diazenyl}phenyl]sulfonyl)-1-ethanol (ADS) is used to impregnate glass fiber filters, and the reagent is oxidized by PAA to the corresponding sulfoxide ADSO. After elution of the filters, ADS and ADSO are separated by reversed-phase HPLC and detected by UV/visible absorbance. Limit of detection is 30 ppb, limit of quantification is 90 ppb (for 30 min sampling), and the linear range comprises 2 orders of magnitude. Thorough investigations were carried out with respect to the selectivity of the method toward hydrogen peroxide, and air samples were analyzed successfully after disinfection of a laboratory area.

Original language	Undefined
Pages (from-to)	6547-6555
Journal	Analytical chemistry
Volume	78
Issue number	18
DOIs	https://doi.org/10.1021/ac060668h
Publication status	Published - 2006

Keywords

IR-74145

Access to Document

10.1021/ac060668h

Cite this

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title = "Passive Sampling of Airborne Peroxyacetic Acid",

abstract = "The first passive sampling device for the determination of airborne peroxyacetic acid (PAA) is presented. 2-([3-{2-[4-Amino-2-(methylsulfanyl)phenyl]-1-diazenyl}phenyl]sulfonyl)-1-ethanol (ADS) is used to impregnate glass fiber filters, and the reagent is oxidized by PAA to the corresponding sulfoxide ADSO. After elution of the filters, ADS and ADSO are separated by reversed-phase HPLC and detected by UV/visible absorbance. Limit of detection is 30 ppb, limit of quantification is 90 ppb (for 30 min sampling), and the linear range comprises 2 orders of magnitude. Thorough investigations were carried out with respect to the selectivity of the method toward hydrogen peroxide, and air samples were analyzed successfully after disinfection of a laboratory area.",

keywords = "IR-74145",

author = "H. Henneken and Laura Assink and {de Wit}, Joyce and M. Vogel and U. Karst",

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doi = "10.1021/ac060668h",

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volume = "78",

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journal = "Analytical chemistry",

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TY - JOUR

T1 - Passive Sampling of Airborne Peroxyacetic Acid

AU - Henneken, H.

AU - Assink, Laura

AU - de Wit, Joyce

AU - Vogel, M.

AU - Karst, U.

PY - 2006

Y1 - 2006

N2 - The first passive sampling device for the determination of airborne peroxyacetic acid (PAA) is presented. 2-([3-{2-[4-Amino-2-(methylsulfanyl)phenyl]-1-diazenyl}phenyl]sulfonyl)-1-ethanol (ADS) is used to impregnate glass fiber filters, and the reagent is oxidized by PAA to the corresponding sulfoxide ADSO. After elution of the filters, ADS and ADSO are separated by reversed-phase HPLC and detected by UV/visible absorbance. Limit of detection is 30 ppb, limit of quantification is 90 ppb (for 30 min sampling), and the linear range comprises 2 orders of magnitude. Thorough investigations were carried out with respect to the selectivity of the method toward hydrogen peroxide, and air samples were analyzed successfully after disinfection of a laboratory area.

AB - The first passive sampling device for the determination of airborne peroxyacetic acid (PAA) is presented. 2-([3-{2-[4-Amino-2-(methylsulfanyl)phenyl]-1-diazenyl}phenyl]sulfonyl)-1-ethanol (ADS) is used to impregnate glass fiber filters, and the reagent is oxidized by PAA to the corresponding sulfoxide ADSO. After elution of the filters, ADS and ADSO are separated by reversed-phase HPLC and detected by UV/visible absorbance. Limit of detection is 30 ppb, limit of quantification is 90 ppb (for 30 min sampling), and the linear range comprises 2 orders of magnitude. Thorough investigations were carried out with respect to the selectivity of the method toward hydrogen peroxide, and air samples were analyzed successfully after disinfection of a laboratory area.

KW - IR-74145

U2 - 10.1021/ac060668h

DO - 10.1021/ac060668h

M3 - Article

SN - 0003-2700

VL - 78

SP - 6547

EP - 6555

JO - Analytical chemistry

JF - Analytical chemistry

IS - 18

ER -