Pb2+ and Cd2+ selective chemically modified field effect transistors based on thioamide functionalized 1,3-alternate calix[4]arenes

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Abstract

Novel calix[4]arenes fixed in the 1,3-alternate conformation and functionalized with thioamide groups have been synthesized and their selectivities for Pb2+ and Cd2+ ions in chemically modified field effect transistors (CHEMFETs) have been evaluated. The 25,27-bis(dimethylaminothiocarbonylmethoxy)-26,28-dipropoxycalix[4]arene 3 in the 1,3-alternate conformation is more selective for Pb2+ than the analogous cone conformer. The 1,3-alternate calix[4]arene 8 having, in the 25- and 27-positions, two pairs of vicinal thioamide moieties at the same face of the molecule, has the highest selectivities for Cd2+ reported so far.
Original languageUndefined
Pages (from-to)1353-1357
JournalJournal of the Chemical Society. Perkin transactions II
Volume1997
Issue number7
DOIs
Publication statusPublished - 1997

Keywords

  • METIS-106004
  • IR-11121

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