Perfluoro effect in the photoelectron spectra of quinoline and isoquinoline

D.M.W. van den Ham, D. van der Meer

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Abstract

The high-resolution He 584Aophotoelectron spectra of heptafluoroquinoline and heptafluoroisoquinoline are compared with those of the parent compounds. Shifts in π ionisation potentials, due to the fluorine substitution, can be described with an inductive and a combined inductive-conjugative Hu¨ckel model.
Original languageEnglish
Pages (from-to)549-552
JournalChemical physics letters
Volume15
Issue number4
DOIs
Publication statusPublished - 1972
Externally publishedYes

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Keywords

  • IR-68127

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