Perovskite-type ceramic membranes ; partial oxidation of methane in a catalytic membrane reactor

F.H.B. Mertins

Perovskite-type ceramic membranes ; partial oxidation of methane in a catalytic membrane reactor

F.H.B. Mertins

Inorganic Materials Science

Research output: Thesis › PhD Thesis - Research UT, graduation UT

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Abstract

The application of mixed ionic and electronic conductors as oxygen separating membranes o®er an attractive alternative for the production of synthesis gas from methane when compared with traditional reforming. Materials with the perovskite structure are the most promising candidates thanks to the ease of tuning their electro-chemical properties with appropriate doping. A number of issues has to be addressed before any industrial breakthrough. The features of interest when using these materials in membrane reactor technology are the magnitude of the oxygen °ux (proportional to the oxygen vacancies concentration) and the thermodynamical stability.

Original language	Undefined
Awarding Institution	University of Twente
Supervisors/Advisors	Blank, Dave, Supervisor Bouwmeester, H.J.M., Supervisor
Award date	17 Mar 2005
Place of Publication	Enschede
Publisher	University of Twente
Print ISBNs	9789036521673
Publication status	Published - 2005

Keywords

IR-50437

Access to Document

thesis_MertinsFinal published version, 2.64 MB

Cite this

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AU - Mertins, F.H.B.

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N2 - The application of mixed ionic and electronic conductors as oxygen separating membranes o®er an attractive alternative for the production of synthesis gas from methane when compared with traditional reforming. Materials with the perovskite structure are the most promising candidates thanks to the ease of tuning their electro-chemical properties with appropriate doping. A number of issues has to be addressed before any industrial breakthrough. The features of interest when using these materials in membrane reactor technology are the magnitude of the oxygen °ux (proportional to the oxygen vacancies concentration) and the thermodynamical stability.

AB - The application of mixed ionic and electronic conductors as oxygen separating membranes o®er an attractive alternative for the production of synthesis gas from methane when compared with traditional reforming. Materials with the perovskite structure are the most promising candidates thanks to the ease of tuning their electro-chemical properties with appropriate doping. A number of issues has to be addressed before any industrial breakthrough. The features of interest when using these materials in membrane reactor technology are the magnitude of the oxygen °ux (proportional to the oxygen vacancies concentration) and the thermodynamical stability.

KW - IR-50437

M3 - PhD Thesis - Research UT, graduation UT

SN - 9789036521673

PB - University of Twente

CY - Enschede

ER -