Phenol extraction with Cyanex 923: Kinetics of the solvent impregnated resin application

Bernhard Burghoff; Edwin Zondervan; Andre B. de Haan

doi:10.1016/j.reactfunctpolym.2009.01.005

Phenol extraction with Cyanex 923: Kinetics of the solvent impregnated resin application

Bernhard Burghoff^*, Edwin Zondervan, Andre B. de Haan

^*Corresponding author for this work

Research output: Contribution to journal › Article › Academic › peer-review

30 Citations (Scopus)

Abstract

In the present work, experimental data concerning the kinetics of phenol extraction with a solvent impregnated resin (SIR) and the description with a kinetic model are presented. Phenol is extracted from aqueous solutions with macroporous polypropylene particles impregnated with Cyanex 923. The rate determining step of the phenol extraction kinetics is identified to be a combination of the complexation between phenol and Cyanex 923 and pore diffusion of phenol inside the SIR. Thus, a model based on chemical reaction and intraparticle diffusion is used to describe the experimental data. Using a sensitivity analysis, it is observed that the diffusivity and the physical equilibrium distribution K_phys have the most pronounced influence on the kinetic model. Increasing the temperature causes an increase of the reaction rate constant and the diffusivity. The kinetic model gives a reasonable fit of the experimentally determined phenol concentration profiles.

Original language	English
Pages (from-to)	264-271
Number of pages	8
Journal	Reactive and Functional Polymers
Volume	69
Issue number	4
DOIs	https://doi.org/10.1016/j.reactfunctpolym.2009.01.005
Publication status	Published - Apr 2009
Externally published	Yes

Keywords

Chromatography
Extraction
Kinetics
Particle
Porous media
Separations

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10.1016/j.reactfunctpolym.2009.01.005

Cite this

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title = "Phenol extraction with Cyanex 923: Kinetics of the solvent impregnated resin application",

abstract = "In the present work, experimental data concerning the kinetics of phenol extraction with a solvent impregnated resin (SIR) and the description with a kinetic model are presented. Phenol is extracted from aqueous solutions with macroporous polypropylene particles impregnated with Cyanex 923. The rate determining step of the phenol extraction kinetics is identified to be a combination of the complexation between phenol and Cyanex 923 and pore diffusion of phenol inside the SIR. Thus, a model based on chemical reaction and intraparticle diffusion is used to describe the experimental data. Using a sensitivity analysis, it is observed that the diffusivity and the physical equilibrium distribution Kphys have the most pronounced influence on the kinetic model. Increasing the temperature causes an increase of the reaction rate constant and the diffusivity. The kinetic model gives a reasonable fit of the experimentally determined phenol concentration profiles.",

keywords = "Chromatography, Extraction, Kinetics, Particle, Porous media, Separations",

author = "Bernhard Burghoff and Edwin Zondervan and {de Haan}, {Andre B.}",

year = "2009",

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doi = "10.1016/j.reactfunctpolym.2009.01.005",

language = "English",

volume = "69",

pages = "264--271",

journal = "Reactive & functional polymers",

issn = "1381-5148",

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TY - JOUR

T1 - Phenol extraction with Cyanex 923

T2 - Kinetics of the solvent impregnated resin application

AU - Burghoff, Bernhard

AU - Zondervan, Edwin

AU - de Haan, Andre B.

PY - 2009/4

Y1 - 2009/4

N2 - In the present work, experimental data concerning the kinetics of phenol extraction with a solvent impregnated resin (SIR) and the description with a kinetic model are presented. Phenol is extracted from aqueous solutions with macroporous polypropylene particles impregnated with Cyanex 923. The rate determining step of the phenol extraction kinetics is identified to be a combination of the complexation between phenol and Cyanex 923 and pore diffusion of phenol inside the SIR. Thus, a model based on chemical reaction and intraparticle diffusion is used to describe the experimental data. Using a sensitivity analysis, it is observed that the diffusivity and the physical equilibrium distribution Kphys have the most pronounced influence on the kinetic model. Increasing the temperature causes an increase of the reaction rate constant and the diffusivity. The kinetic model gives a reasonable fit of the experimentally determined phenol concentration profiles.

AB - In the present work, experimental data concerning the kinetics of phenol extraction with a solvent impregnated resin (SIR) and the description with a kinetic model are presented. Phenol is extracted from aqueous solutions with macroporous polypropylene particles impregnated with Cyanex 923. The rate determining step of the phenol extraction kinetics is identified to be a combination of the complexation between phenol and Cyanex 923 and pore diffusion of phenol inside the SIR. Thus, a model based on chemical reaction and intraparticle diffusion is used to describe the experimental data. Using a sensitivity analysis, it is observed that the diffusivity and the physical equilibrium distribution Kphys have the most pronounced influence on the kinetic model. Increasing the temperature causes an increase of the reaction rate constant and the diffusivity. The kinetic model gives a reasonable fit of the experimentally determined phenol concentration profiles.

KW - Chromatography

KW - Extraction

KW - Kinetics

KW - Particle

KW - Porous media

KW - Separations

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U2 - 10.1016/j.reactfunctpolym.2009.01.005

DO - 10.1016/j.reactfunctpolym.2009.01.005

M3 - Article

AN - SCOPUS:61449224430

VL - 69

SP - 264

EP - 271

JO - Reactive & functional polymers

JF - Reactive & functional polymers

SN - 1381-5148

IS - 4

ER -

Phenol extraction with Cyanex 923: Kinetics of the solvent impregnated resin application

Abstract

Keywords

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