Photo-induced switchable binding behavior of bridged bis(ß-cyclodextrin) with an azobenzene dicarboxylate linker

Yu Liu, Shu Kang, Yong Chen, Y. Chen, Ying-Wei Yang, Jurriaan Huskens

Research output: Contribution to journalArticleAcademicpeer-review

16 Citations (Scopus)

Abstract

A bridged bis(β-cyclodextrin) (1) with an azobenzene dicarboxylate linker was synthesized, and its binding behavior with a fluorescent dye, acridine red (AR), was investigated by means of fluorescence spectroscopy. Due to the photo-induced conversion of the azobenzene dicarboxylate linker from the trans-conformer to the cis-conformer, 1 exhibits a different binding behavior before and after UV light irradiation, giving a stronger binding ability towards AR in the cis form. This switchable binding behavior of 1 may open a new channel to the design of azobenzene-linked dimeric receptors as photo-induced molecular devices
Original languageUndefined
Pages (from-to)197-201
Number of pages5
JournalJournal of inclusion phenomena and macrocyclic chemistry
Volume56
Issue number1-2
DOIs
Publication statusPublished - 2006

Keywords

  • METIS-243475
  • IR-74504

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