Photo-induced switchable binding behavior of bridged bis(ß-cyclodextrin) with an azobenzene dicarboxylate linker

Yu Liu; Shu Kang; Yong Chen; Y. Chen; Ying-Wei Yang; Jurriaan Huskens

doi:10.1007/s10847-006-9083-4

Photo-induced switchable binding behavior of bridged bis(ß-cyclodextrin) with an azobenzene dicarboxylate linker

Yu Liu, Shu Kang, Yong Chen, Y. Chen, Ying-Wei Yang, Jurriaan Huskens

Research output: Contribution to journal › Article › Academic › peer-review

18 Citations (Scopus)

Abstract

A bridged bis(β-cyclodextrin) (1) with an azobenzene dicarboxylate linker was synthesized, and its binding behavior with a fluorescent dye, acridine red (AR), was investigated by means of fluorescence spectroscopy. Due to the photo-induced conversion of the azobenzene dicarboxylate linker from the trans-conformer to the cis-conformer, 1 exhibits a different binding behavior before and after UV light irradiation, giving a stronger binding ability towards AR in the cis form. This switchable binding behavior of 1 may open a new channel to the design of azobenzene-linked dimeric receptors as photo-induced molecular devices

Original language	Undefined
Pages (from-to)	197-201
Number of pages	5
Journal	Journal of inclusion phenomena and macrocyclic chemistry
Volume	56
Issue number	1-2
DOIs	https://doi.org/10.1007/s10847-006-9083-4
Publication status	Published - 2006

Keywords

METIS-243475
IR-74504

Access to Document

10.1007/s10847-006-9083-4

Cite this

@article{63532a24e2f8430fbd7395a6a2a972c8,

title = "Photo-induced switchable binding behavior of bridged bis({\ss}-cyclodextrin) with an azobenzene dicarboxylate linker",

abstract = "A bridged bis(β-cyclodextrin) (1) with an azobenzene dicarboxylate linker was synthesized, and its binding behavior with a fluorescent dye, acridine red (AR), was investigated by means of fluorescence spectroscopy. Due to the photo-induced conversion of the azobenzene dicarboxylate linker from the trans-conformer to the cis-conformer, 1 exhibits a different binding behavior before and after UV light irradiation, giving a stronger binding ability towards AR in the cis form. This switchable binding behavior of 1 may open a new channel to the design of azobenzene-linked dimeric receptors as photo-induced molecular devices",

keywords = "METIS-243475, IR-74504",

author = "Yu Liu and Shu Kang and Yong Chen and Y. Chen and Ying-Wei Yang and Jurriaan Huskens",

note = "From the issue entitled {"}Special Issue: 3rd Asian Cyclodextrin Conference (ACC2005) ",

year = "2006",

doi = "10.1007/s10847-006-9083-4",

language = "Undefined",

volume = "56",

pages = "197--201",

journal = "Journal of inclusion phenomena and macrocyclic chemistry",

issn = "1388-3127",

publisher = "Kluwer Academic Publishers",

number = "1-2",

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TY - JOUR

T1 - Photo-induced switchable binding behavior of bridged bis(ß-cyclodextrin) with an azobenzene dicarboxylate linker

AU - Liu, Yu

AU - Kang, Shu

AU - Chen, Yong

AU - Chen, Y.

AU - Yang, Ying-Wei

AU - Huskens, Jurriaan

N1 - From the issue entitled "Special Issue: 3rd Asian Cyclodextrin Conference (ACC2005)

PY - 2006

Y1 - 2006

N2 - A bridged bis(β-cyclodextrin) (1) with an azobenzene dicarboxylate linker was synthesized, and its binding behavior with a fluorescent dye, acridine red (AR), was investigated by means of fluorescence spectroscopy. Due to the photo-induced conversion of the azobenzene dicarboxylate linker from the trans-conformer to the cis-conformer, 1 exhibits a different binding behavior before and after UV light irradiation, giving a stronger binding ability towards AR in the cis form. This switchable binding behavior of 1 may open a new channel to the design of azobenzene-linked dimeric receptors as photo-induced molecular devices

AB - A bridged bis(β-cyclodextrin) (1) with an azobenzene dicarboxylate linker was synthesized, and its binding behavior with a fluorescent dye, acridine red (AR), was investigated by means of fluorescence spectroscopy. Due to the photo-induced conversion of the azobenzene dicarboxylate linker from the trans-conformer to the cis-conformer, 1 exhibits a different binding behavior before and after UV light irradiation, giving a stronger binding ability towards AR in the cis form. This switchable binding behavior of 1 may open a new channel to the design of azobenzene-linked dimeric receptors as photo-induced molecular devices

KW - METIS-243475

KW - IR-74504

U2 - 10.1007/s10847-006-9083-4

DO - 10.1007/s10847-006-9083-4

M3 - Article

VL - 56

SP - 197

EP - 201

JO - Journal of inclusion phenomena and macrocyclic chemistry

JF - Journal of inclusion phenomena and macrocyclic chemistry

SN - 1388-3127

IS - 1-2

ER -