TY - JOUR
T1 - Photoelectron spectra of some fluorine substituted diazanaphthalenes
AU - van den Ham, D.M.W.
AU - van der Meer, D.
PY - 1973
Y1 - 1973
N2 - The high resolution He 584 Å photoelectron spectra of fluorine substituted 1,2-diaza-, 1,3-diaza-, 1,4-diaza- and 2,3-diaza-naphthalene are presented. By means of fluorine substitution the analysis of the photoelectron spectra of the parent compounds can be made more definite. Unexpected shifts of the nitrogen “lone-pair” bands can be explained within the through-space and through-bond interaction model. From this explanation one can deduce that fluorine substitution can give experimental evidence about the symmetry character of the “lone-pair” molecular orbitals.
AB - The high resolution He 584 Å photoelectron spectra of fluorine substituted 1,2-diaza-, 1,3-diaza-, 1,4-diaza- and 2,3-diaza-naphthalene are presented. By means of fluorine substitution the analysis of the photoelectron spectra of the parent compounds can be made more definite. Unexpected shifts of the nitrogen “lone-pair” bands can be explained within the through-space and through-bond interaction model. From this explanation one can deduce that fluorine substitution can give experimental evidence about the symmetry character of the “lone-pair” molecular orbitals.
U2 - 10.1016/0368-2048(73)80017-9
DO - 10.1016/0368-2048(73)80017-9
M3 - Article
SN - 0368-2048
VL - 2
SP - 247
EP - 258
JO - Journal of electron spectroscopy and related phenomena
JF - Journal of electron spectroscopy and related phenomena
IS - 3
ER -