Plasma polymerization surface modification of Carbon black and its effect in elastomers

Tony Mathew; Rabin N. Datta; Wilma K. Dierkes; Auke G. Talma; Wim J. van Ooij; Jacques W.M. Noordermeer

doi:10.1002/mame.201000252

Plasma polymerization surface modification of Carbon black and its effect in elastomers

Tony Mathew, Rabin N. Datta, Wilma K. Dierkes, Auke G. Talma, Wim J. van Ooij, Jacques W.M. Noordermeer^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › Academic › peer-review

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Abstract

Surface modification of carbon black by plasma polymerization was aimed to reduce its surface energy in order to compatibilize the filler with various elastomers. A fullerenic carbon black was used for the modification process. Thermogravimetric analysis, wetting behavior with liquids of known surface tension, TEM and TOF-SIMS were used to characterize the carbon black before and after modification. The state of plasma-coated carbon black in rubber was studied by means of conductivity measurements. The behavior of the modified filler in rubber was studied using the Payne effect and stress/strain properties. The study shows that plasma-coated carbon black results in a better dispersion in different rubber systems than the uncoated version.

Original language	English
Pages (from-to)	42-52
Number of pages	10
Journal	Macromolecular materials and engineering
Volume	296
Issue number	1
DOIs	https://doi.org/10.1002/mame.201000252
Publication status	Published - 16 Nov 2011

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title = "Plasma polymerization surface modification of Carbon black and its effect in elastomers",

abstract = "Surface modification of carbon black by plasma polymerization was aimed to reduce its surface energy in order to compatibilize the filler with various elastomers. A fullerenic carbon black was used for the modification process. Thermogravimetric analysis, wetting behavior with liquids of known surface tension, TEM and TOF-SIMS were used to characterize the carbon black before and after modification. The state of plasma-coated carbon black in rubber was studied by means of conductivity measurements. The behavior of the modified filler in rubber was studied using the Payne effect and stress/strain properties. The study shows that plasma-coated carbon black results in a better dispersion in different rubber systems than the uncoated version.",

author = "Tony Mathew and Datta, {Rabin N.} and Dierkes, {Wilma K.} and Talma, {Auke G.} and {van Ooij}, {Wim J.} and Noordermeer, {Jacques W.M.}",

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AU - Mathew, Tony

AU - Datta, Rabin N.

AU - Dierkes, Wilma K.

AU - Talma, Auke G.

AU - van Ooij, Wim J.

AU - Noordermeer, Jacques W.M.

PY - 2011/11/16

Y1 - 2011/11/16

N2 - Surface modification of carbon black by plasma polymerization was aimed to reduce its surface energy in order to compatibilize the filler with various elastomers. A fullerenic carbon black was used for the modification process. Thermogravimetric analysis, wetting behavior with liquids of known surface tension, TEM and TOF-SIMS were used to characterize the carbon black before and after modification. The state of plasma-coated carbon black in rubber was studied by means of conductivity measurements. The behavior of the modified filler in rubber was studied using the Payne effect and stress/strain properties. The study shows that plasma-coated carbon black results in a better dispersion in different rubber systems than the uncoated version.

AB - Surface modification of carbon black by plasma polymerization was aimed to reduce its surface energy in order to compatibilize the filler with various elastomers. A fullerenic carbon black was used for the modification process. Thermogravimetric analysis, wetting behavior with liquids of known surface tension, TEM and TOF-SIMS were used to characterize the carbon black before and after modification. The state of plasma-coated carbon black in rubber was studied by means of conductivity measurements. The behavior of the modified filler in rubber was studied using the Payne effect and stress/strain properties. The study shows that plasma-coated carbon black results in a better dispersion in different rubber systems than the uncoated version.

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DO - 10.1002/mame.201000252

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JO - Macromolecular materials and engineering

JF - Macromolecular materials and engineering

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Plasma polymerization surface modification of Carbon black and its effect in elastomers

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