Plutonium(IV) complexation by diglycolamide ligands - coordination chemistry insight into TODGA-based actinide separations

S.D. Reilly; A.J. Gaunt; B.L. Scott; G. Modolo; M. Iqbal; Willem Verboom; M.J. Sarsfield

doi:10.1039/c2cc34967a

Plutonium(IV) complexation by diglycolamide ligands - coordination chemistry insight into TODGA-based actinide separations

S.D. Reilly, A.J. Gaunt, B.L. Scott, G. Modolo, M. Iqbal, Willem Verboom, M.J. Sarsfield

Research output: Contribution to journal › Article › Academic › peer-review

60 Citations (Scopus)

Abstract

Complexation of Pu(IV) with TMDGA, TEDGA, and TODGA diglycolamide ligands was followed by vis-NIR spectroscopy. A crystal structure determination reveals that TMDGA forms a 1:3 homoleptic Pu(IV) complex with the nitrate anions forced into the outer coordination sphere

Original language	Undefined
Pages (from-to)	9732-9734
Number of pages	2
Journal	Chemical communications
Volume	48
Issue number	78
DOIs	https://doi.org/10.1039/c2cc34967a
Publication status	Published - 2012

Keywords

METIS-293811
IR-85055

Access to Document

10.1039/c2cc34967a

Cite this

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title = "Plutonium(IV) complexation by diglycolamide ligands - coordination chemistry insight into TODGA-based actinide separations",

abstract = "Complexation of Pu(IV) with TMDGA, TEDGA, and TODGA diglycolamide ligands was followed by vis-NIR spectroscopy. A crystal structure determination reveals that TMDGA forms a 1:3 homoleptic Pu(IV) complex with the nitrate anions forced into the outer coordination sphere",

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T1 - Plutonium(IV) complexation by diglycolamide ligands - coordination chemistry insight into TODGA-based actinide separations

AU - Reilly, S.D.

AU - Gaunt, A.J.

AU - Scott, B.L.

AU - Modolo, G.

AU - Iqbal, M.

AU - Verboom, Willem

AU - Sarsfield, M.J.

PY - 2012

Y1 - 2012

N2 - Complexation of Pu(IV) with TMDGA, TEDGA, and TODGA diglycolamide ligands was followed by vis-NIR spectroscopy. A crystal structure determination reveals that TMDGA forms a 1:3 homoleptic Pu(IV) complex with the nitrate anions forced into the outer coordination sphere

AB - Complexation of Pu(IV) with TMDGA, TEDGA, and TODGA diglycolamide ligands was followed by vis-NIR spectroscopy. A crystal structure determination reveals that TMDGA forms a 1:3 homoleptic Pu(IV) complex with the nitrate anions forced into the outer coordination sphere

KW - METIS-293811

KW - IR-85055

U2 - 10.1039/c2cc34967a

DO - 10.1039/c2cc34967a

M3 - Article

VL - 48

SP - 9732

EP - 9734

JO - Chemical communications

JF - Chemical communications

SN - 1359-7345

IS - 78

ER -