Plutonium(IV) complexation by diglycolamide ligands - coordination chemistry insight into TODGA-based actinide separations

S.D. Reilly, A.J. Gaunt, B.L. Scott, G. Modolo, M. Iqbal, Willem Verboom, M.J. Sarsfield

Research output: Contribution to journalArticleAcademicpeer-review

60 Citations (Scopus)


Complexation of Pu(IV) with TMDGA, TEDGA, and TODGA diglycolamide ligands was followed by vis-NIR spectroscopy. A crystal structure determination reveals that TMDGA forms a 1:3 homoleptic Pu(IV) complex with the nitrate anions forced into the outer coordination sphere
Original languageUndefined
Pages (from-to)9732-9734
Number of pages2
JournalChemical communications
Issue number78
Publication statusPublished - 2012


  • METIS-293811
  • IR-85055

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