Poly(alkylidene chlorophosphate)s via acyclic diene metathesis polymerization: A general platform for the postpolymerization modification of poly(phosphoester)s

Mark Steinmann; Jens Markwart; Frederik R. Wurm

doi:10.1021/ma501959h

Poly(alkylidene chlorophosphate)s via acyclic diene metathesis polymerization: A general platform for the postpolymerization modification of poly(phosphoester)s

Mark Steinmann, Jens Markwart, Frederik R. Wurm^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › Academic › peer-review

24 Citations (Scopus)

Abstract

Reactive poly(phosphoester)s (PPEs) have been prepared via the acyclic diene metathesis polymerization of the monomers di(buten-3-yl) chlorophosphate and di(undecen-10-yl) chlorophosphate. Molecular weights can be adjusted from 3000 to ca. 50 000 g/mol and have been prepared and characterized in detail. This is the first report on olefin metathesis polymerization of highly electrophilic phosphochlorides, which were postmodified with different nucleophiles, i.e., alcohols, amines, and water, thus allowing the synthesis of side chain polyphosphoamidates, poly(phosphoester)s, and free acids from the same starting polymer. High side-chain functionality was found in all cases.

Original language	English
Pages (from-to)	8506-8513
Number of pages	8
Journal	Macromolecules
Volume	47
Issue number	24
DOIs	https://doi.org/10.1021/ma501959h
Publication status	Published - 23 Dec 2014
Externally published	Yes

Access to Document

10.1021/ma501959h

Cite this

@article{f083e501821a4bca80a9fa1d995fb067,

title = "Poly(alkylidene chlorophosphate)s via acyclic diene metathesis polymerization: A general platform for the postpolymerization modification of poly(phosphoester)s",

abstract = "Reactive poly(phosphoester)s (PPEs) have been prepared via the acyclic diene metathesis polymerization of the monomers di(buten-3-yl) chlorophosphate and di(undecen-10-yl) chlorophosphate. Molecular weights can be adjusted from 3000 to ca. 50 000 g/mol and have been prepared and characterized in detail. This is the first report on olefin metathesis polymerization of highly electrophilic phosphochlorides, which were postmodified with different nucleophiles, i.e., alcohols, amines, and water, thus allowing the synthesis of side chain polyphosphoamidates, poly(phosphoester)s, and free acids from the same starting polymer. High side-chain functionality was found in all cases.",

author = "Mark Steinmann and Jens Markwart and Wurm, {Frederik R.}",

year = "2014",

month = dec,

day = "23",

doi = "10.1021/ma501959h",

language = "English",

volume = "47",

pages = "8506--8513",

journal = "Macromolecules",

issn = "0024-9297",

publisher = "American Chemical Society",

number = "24",

}

TY - JOUR

T1 - Poly(alkylidene chlorophosphate)s via acyclic diene metathesis polymerization

T2 - A general platform for the postpolymerization modification of poly(phosphoester)s

AU - Steinmann, Mark

AU - Markwart, Jens

AU - Wurm, Frederik R.

PY - 2014/12/23

Y1 - 2014/12/23

N2 - Reactive poly(phosphoester)s (PPEs) have been prepared via the acyclic diene metathesis polymerization of the monomers di(buten-3-yl) chlorophosphate and di(undecen-10-yl) chlorophosphate. Molecular weights can be adjusted from 3000 to ca. 50 000 g/mol and have been prepared and characterized in detail. This is the first report on olefin metathesis polymerization of highly electrophilic phosphochlorides, which were postmodified with different nucleophiles, i.e., alcohols, amines, and water, thus allowing the synthesis of side chain polyphosphoamidates, poly(phosphoester)s, and free acids from the same starting polymer. High side-chain functionality was found in all cases.

AB - Reactive poly(phosphoester)s (PPEs) have been prepared via the acyclic diene metathesis polymerization of the monomers di(buten-3-yl) chlorophosphate and di(undecen-10-yl) chlorophosphate. Molecular weights can be adjusted from 3000 to ca. 50 000 g/mol and have been prepared and characterized in detail. This is the first report on olefin metathesis polymerization of highly electrophilic phosphochlorides, which were postmodified with different nucleophiles, i.e., alcohols, amines, and water, thus allowing the synthesis of side chain polyphosphoamidates, poly(phosphoester)s, and free acids from the same starting polymer. High side-chain functionality was found in all cases.

UR - http://www.scopus.com/inward/record.url?scp=84919741143&partnerID=8YFLogxK

U2 - 10.1021/ma501959h

DO - 10.1021/ma501959h

M3 - Article

AN - SCOPUS:84919741143

VL - 47

SP - 8506

EP - 8513

JO - Macromolecules

JF - Macromolecules

SN - 0024-9297

IS - 24

ER -

Poly(alkylidene chlorophosphate)s via acyclic diene metathesis polymerization: A general platform for the postpolymerization modification of poly(phosphoester)s

Abstract

Access to Document

Other files and links

Fingerprint

Cite this