Poly(ferrocenylsilane) electrolytes as a gold nanoparticle foundry: "two-in-one" redox synthesis and electrosteric stabilization, and sensing applications

Y. N. Tan, Dominik Jańczewski, M. A. Hempenius, J. W. Xu, H. R. Tan, G. J. Vancso

Research output: Contribution to journalArticleAcademicpeer-review

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Abstract

Gold nanoparticles (AuNPs) coated with responsive polymers gained considerable interest due to their controllable size, good stability, and fast environmental response suitable for biological applications and sensing. Here we report on a simple and efficient method for the synthesis of stable and redox responsive AuNPs using organometallic polyelectrolytes in aqueous solutions of HAuCl4. In the redox reaction, positively or negatively charged poly(ferrocenylsilanes) (PFS+/PFS-) served as reducing agents, and also as stabilizing polymers. Due to their unique tunable electrostatic and electrosteric protection, AuNPs coated with PFS-, (PFS+)@AuNPs, possess high redox sensitivity, with reversible, repetitive, sustainable color switching between the assembled (purple color) and disassembled (red color) states as evidenced by UV-Vis absorption and TEM measurements. Feasibility studies reported here indicate that the particles described can be applied as a colorimetric probe for the detection of redox molecules, e.g. vitamin C, in a controlled and facile manner.

Original languageEnglish
Pages (from-to)19255-19262
Number of pages8
JournalNanoscale
Volume9
Issue number48
DOIs
Publication statusPublished - 28 Dec 2017

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Foundries
Gold
Electrolytes
Stabilization
Nanoparticles
Color
Polymers
Redox reactions
Vitamins
Reducing Agents
Reducing agents
Organometallics
Polyelectrolytes
Ascorbic Acid
Electrostatics
Transmission electron microscopy
Molecules
Oxidation-Reduction
poly(ferrocenylsilane)

Cite this

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title = "Poly(ferrocenylsilane) electrolytes as a gold nanoparticle foundry: {"}two-in-one{"} redox synthesis and electrosteric stabilization, and sensing applications",
abstract = "Gold nanoparticles (AuNPs) coated with responsive polymers gained considerable interest due to their controllable size, good stability, and fast environmental response suitable for biological applications and sensing. Here we report on a simple and efficient method for the synthesis of stable and redox responsive AuNPs using organometallic polyelectrolytes in aqueous solutions of HAuCl4. In the redox reaction, positively or negatively charged poly(ferrocenylsilanes) (PFS+/PFS-) served as reducing agents, and also as stabilizing polymers. Due to their unique tunable electrostatic and electrosteric protection, AuNPs coated with PFS-, (PFS+)@AuNPs, possess high redox sensitivity, with reversible, repetitive, sustainable color switching between the assembled (purple color) and disassembled (red color) states as evidenced by UV-Vis absorption and TEM measurements. Feasibility studies reported here indicate that the particles described can be applied as a colorimetric probe for the detection of redox molecules, e.g. vitamin C, in a controlled and facile manner.",
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Poly(ferrocenylsilane) electrolytes as a gold nanoparticle foundry : "two-in-one" redox synthesis and electrosteric stabilization, and sensing applications. / Tan, Y. N.; Jańczewski, Dominik; Hempenius, M. A.; Xu, J. W.; Tan, H. R.; Vancso, G. J.

In: Nanoscale, Vol. 9, No. 48, 28.12.2017, p. 19255-19262.

Research output: Contribution to journalArticleAcademicpeer-review

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