TY - JOUR
T1 - Polymerization of propadiene. II. Catalyst systems based on 3d transition metals and various stabilizing ligands
AU - van den Enk, J.E.
AU - van der Ploeg, H.J.
PY - 1971
Y1 - 1971
N2 - A variety of catalyst systems based on 3d transition metals, i.e., V(III), Cr(III), Mn(II), Fe(II), Co(II), Ni(II), Cu(II), and various stabilizing ligands, i.e., propadiene, methylacetylene, phenylacetylene, and 1,4-butadiene, were prepared. The activity of these catalytic systems towards the polymerization of a series of monomers (propadiene, methylacetylene, phenylacetylene, 1,4-butadiene, ethene, and propene) is investigated. Optimum conditions for the preparation of 1,2-polyallene, polymethylacetylene and polyphenylacetylene are given.
AB - A variety of catalyst systems based on 3d transition metals, i.e., V(III), Cr(III), Mn(II), Fe(II), Co(II), Ni(II), Cu(II), and various stabilizing ligands, i.e., propadiene, methylacetylene, phenylacetylene, and 1,4-butadiene, were prepared. The activity of these catalytic systems towards the polymerization of a series of monomers (propadiene, methylacetylene, phenylacetylene, 1,4-butadiene, ethene, and propene) is investigated. Optimum conditions for the preparation of 1,2-polyallene, polymethylacetylene and polyphenylacetylene are given.
U2 - 10.1002/pol.1971.150090826
DO - 10.1002/pol.1971.150090826
M3 - Article
SN - 0449-296X
VL - 9
SP - 2403
EP - 2407
JO - Journal of Polymer Science, Part A-1: Polymer chemistry
JF - Journal of Polymer Science, Part A-1: Polymer chemistry
IS - 8
ER -