A variety of catalyst systems based on 3d transition metals, i.e., V(III), Cr(III), Mn(II), Fe(II), Co(II), Ni(II), Cu(II), and various stabilizing ligands, i.e., propadiene, methylacetylene, phenylacetylene, and 1,4-butadiene, were prepared. The activity of these catalytic systems towards the polymerization of a series of monomers (propadiene, methylacetylene, phenylacetylene, 1,4-butadiene, ethene, and propene) is investigated. Optimum conditions for the preparation of 1,2-polyallene, polymethylacetylene and polyphenylacetylene are given.
|Journal||Journal of Polymer Science, Part A-1: Polymer chemistry|
|Publication status||Published - 1971|
van den Enk, J. E., & van der Ploeg, H. J. (1971). Polymerization of propadiene. II. Catalyst systems based on 3d transition metals and various stabilizing ligands. Journal of Polymer Science, Part A-1: Polymer chemistry, 9(8), 2403-2407. https://doi.org/10.1002/pol.1971.150090826