Polymerization of propadiene. III. Catalyst systems based on various rhodium (I) complexes

J.P. Scholten; H.J. van der Ploeg

doi:10.1002/pol.1972.170101023

Polymerization of propadiene. III. Catalyst systems based on various rhodium (I) complexes

J.P. Scholten, H.J. van der Ploeg

Faculty of Science and Technology

Research output: Contribution to journal › Article › Academic › peer-review

40 Downloads (Pure)

Abstract

The polymerization of propadiene to 1,2-polyallene by various Rh(I) based catalysts is described and discussed. Also the interrelations between these Rh(I) complexes are discussed and an overall reaction scheme is given. A mechanism is put forward in which the formation of a common intermediate from propadiene and different Rh(I) complexes is the rate determining step. It is found that the activity decreases in the order: cis-Rh(CO)2P(C6H5)3Cl > [Rh(CO)2Cl]2 > Rh(CO)3Cl. The complexes Rh[P(C6H5)3]2(CO)Cl and Rh[P(C6H5)3]3Cl proved to be inactive in the polymerization of propadiene.

Original language	English
Pages (from-to)	3067-3076
Journal	Journal of Polymer Science: Polymer Chemistry Edition
Volume	10
Issue number	10
DOIs	https://doi.org/10.1002/pol.1972.170101023
Publication status	Published - 1972

Access to Document

10.1002/pol.1972.170101023

Scholten72poly3Final published version, 466 KB

Cite this

@article{b21cb1f3eb0045f9b8c8f76365758b45,

title = "Polymerization of propadiene. III. Catalyst systems based on various rhodium (I) complexes",

abstract = "The polymerization of propadiene to 1,2-polyallene by various Rh(I) based catalysts is described and discussed. Also the interrelations between these Rh(I) complexes are discussed and an overall reaction scheme is given. A mechanism is put forward in which the formation of a common intermediate from propadiene and different Rh(I) complexes is the rate determining step. It is found that the activity decreases in the order: cis-Rh(CO)2P(C6H5)3Cl > [Rh(CO)2Cl]2 > Rh(CO)3Cl. The complexes Rh[P(C6H5)3]2(CO)Cl and Rh[P(C6H5)3]3Cl proved to be inactive in the polymerization of propadiene.",

author = "J.P. Scholten and {van der Ploeg}, H.J.",

year = "1972",

doi = "10.1002/pol.1972.170101023",

language = "English",

volume = "10",

pages = "3067--3076",

journal = "Journal of Polymer Science: Polymer Chemistry Edition",

issn = "0360-6376",

publisher = "Wiley",

number = "10",

}

TY - JOUR

T1 - Polymerization of propadiene. III. Catalyst systems based on various rhodium (I) complexes

AU - Scholten, J.P.

AU - van der Ploeg, H.J.

PY - 1972

Y1 - 1972

N2 - The polymerization of propadiene to 1,2-polyallene by various Rh(I) based catalysts is described and discussed. Also the interrelations between these Rh(I) complexes are discussed and an overall reaction scheme is given. A mechanism is put forward in which the formation of a common intermediate from propadiene and different Rh(I) complexes is the rate determining step. It is found that the activity decreases in the order: cis-Rh(CO)2P(C6H5)3Cl > [Rh(CO)2Cl]2 > Rh(CO)3Cl. The complexes Rh[P(C6H5)3]2(CO)Cl and Rh[P(C6H5)3]3Cl proved to be inactive in the polymerization of propadiene.

AB - The polymerization of propadiene to 1,2-polyallene by various Rh(I) based catalysts is described and discussed. Also the interrelations between these Rh(I) complexes are discussed and an overall reaction scheme is given. A mechanism is put forward in which the formation of a common intermediate from propadiene and different Rh(I) complexes is the rate determining step. It is found that the activity decreases in the order: cis-Rh(CO)2P(C6H5)3Cl > [Rh(CO)2Cl]2 > Rh(CO)3Cl. The complexes Rh[P(C6H5)3]2(CO)Cl and Rh[P(C6H5)3]3Cl proved to be inactive in the polymerization of propadiene.

U2 - 10.1002/pol.1972.170101023

DO - 10.1002/pol.1972.170101023

M3 - Article

SN - 0360-6376

VL - 10

SP - 3067

EP - 3076

JO - Journal of Polymer Science: Polymer Chemistry Edition

JF - Journal of Polymer Science: Polymer Chemistry Edition

IS - 10

ER -

Polymerization of propadiene. III. Catalyst systems based on various rhodium (I) complexes

Abstract

Access to Document

Fingerprint

Cite this