POSS-based poly(aryl ether sulfone)s random terpolymer linked POSS to the main chain: effect of chemical structure and POSS content on properties

Yanfeng Wei; Qiyang Jiang; Jinmeng Hao; Jianxin Mu

doi:10.1002/pat.3949

POSS-based poly(aryl ether sulfone)s random terpolymer linked POSS to the main chain: effect of chemical structure and POSS content on properties

Yanfeng Wei
, Qiyang Jiang
, Jinmeng Hao
, Jianxin Mu^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › Academic › peer-review

5 Citations (Scopus)

Abstract

In order to investigate the effect of polyhedral oligomeric silsesquioxane content and the structure-function related on the dielectric property and hydrophobicity, three kinds of poly(aryl ether sulfone)s (PAESs) random terpolymer with different chemistry structure at variable polyhedral oligomeric silsesquioxane content in the main chain are prepared. The structures of PAESs are characterized by infrared (IR), nuclear magnetic resonance (NMR), and wide-angle X-ray diffraction (WXRD) spectra. The results show that the dielectric constant initially increases then decrease to 2.68 at 100%-double-decker silsesquioxane (DDSQ)-PAES(molar content of DDSQ = 100%) at 1 MHz. The contact angle increased to 97.5° at 100%-DDSQ-PAES. While the chemical structure of organic chains also plays an important role on thermostability, dielectric, and hydrophobic properties. The results are discussed and interpreted in detail.

Original language	English
Pages (from-to)	516-523
Number of pages	8
Journal	Polymers for advanced technologies
Volume	28
Issue number	4
DOIs	https://doi.org/10.1002/pat.3949
Publication status	Published - 1 Apr 2017
Externally published	Yes

Keywords

hydrophobic property
low dielectric constant
poly(arylene ether sulfone)s
polyhedral oligomeric silsesquioxanes

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10.1002/pat.3949

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@article{29c9cfb684704ce2a38cc5944ff33e1f,

title = "POSS-based poly(aryl ether sulfone)s random terpolymer linked POSS to the main chain: effect of chemical structure and POSS content on properties",

abstract = "In order to investigate the effect of polyhedral oligomeric silsesquioxane content and the structure-function related on the dielectric property and hydrophobicity, three kinds of poly(aryl ether sulfone)s (PAESs) random terpolymer with different chemistry structure at variable polyhedral oligomeric silsesquioxane content in the main chain are prepared. The structures of PAESs are characterized by infrared (IR), nuclear magnetic resonance (NMR), and wide-angle X-ray diffraction (WXRD) spectra. The results show that the dielectric constant initially increases then decrease to 2.68 at 100\%-double-decker silsesquioxane (DDSQ)-PAES(molar content of DDSQ = 100\%) at 1 MHz. The contact angle increased to 97.5° at 100\%-DDSQ-PAES. While the chemical structure of organic chains also plays an important role on thermostability, dielectric, and hydrophobic properties. The results are discussed and interpreted in detail.",

keywords = "hydrophobic property, low dielectric constant, poly(arylene ether sulfone)s, polyhedral oligomeric silsesquioxanes",

author = "Yanfeng Wei and Qiyang Jiang and Jinmeng Hao and Jianxin Mu",

year = "2017",

month = apr,

day = "1",

doi = "10.1002/pat.3949",

language = "English",

volume = "28",

pages = "516--523",

journal = "Polymers for advanced technologies",

issn = "1042-7147",

publisher = "Wiley",

number = "4",

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TY - JOUR

T1 - POSS-based poly(aryl ether sulfone)s random terpolymer linked POSS to the main chain

T2 - effect of chemical structure and POSS content on properties

AU - Wei, Yanfeng

AU - Jiang, Qiyang

AU - Hao, Jinmeng

AU - Mu, Jianxin

PY - 2017/4/1

Y1 - 2017/4/1

N2 - In order to investigate the effect of polyhedral oligomeric silsesquioxane content and the structure-function related on the dielectric property and hydrophobicity, three kinds of poly(aryl ether sulfone)s (PAESs) random terpolymer with different chemistry structure at variable polyhedral oligomeric silsesquioxane content in the main chain are prepared. The structures of PAESs are characterized by infrared (IR), nuclear magnetic resonance (NMR), and wide-angle X-ray diffraction (WXRD) spectra. The results show that the dielectric constant initially increases then decrease to 2.68 at 100%-double-decker silsesquioxane (DDSQ)-PAES(molar content of DDSQ = 100%) at 1 MHz. The contact angle increased to 97.5° at 100%-DDSQ-PAES. While the chemical structure of organic chains also plays an important role on thermostability, dielectric, and hydrophobic properties. The results are discussed and interpreted in detail.

AB - In order to investigate the effect of polyhedral oligomeric silsesquioxane content and the structure-function related on the dielectric property and hydrophobicity, three kinds of poly(aryl ether sulfone)s (PAESs) random terpolymer with different chemistry structure at variable polyhedral oligomeric silsesquioxane content in the main chain are prepared. The structures of PAESs are characterized by infrared (IR), nuclear magnetic resonance (NMR), and wide-angle X-ray diffraction (WXRD) spectra. The results show that the dielectric constant initially increases then decrease to 2.68 at 100%-double-decker silsesquioxane (DDSQ)-PAES(molar content of DDSQ = 100%) at 1 MHz. The contact angle increased to 97.5° at 100%-DDSQ-PAES. While the chemical structure of organic chains also plays an important role on thermostability, dielectric, and hydrophobic properties. The results are discussed and interpreted in detail.

KW - hydrophobic property

KW - low dielectric constant

KW - poly(arylene ether sulfone)s

KW - polyhedral oligomeric silsesquioxanes

UR - https://www.scopus.com/pages/publications/84989306577

U2 - 10.1002/pat.3949

DO - 10.1002/pat.3949

M3 - Article

AN - SCOPUS:84989306577

SN - 1042-7147

VL - 28

SP - 516

EP - 523

JO - Polymers for advanced technologies

JF - Polymers for advanced technologies

IS - 4

ER -

POSS-based poly(aryl ether sulfone)s random terpolymer linked POSS to the main chain: effect of chemical structure and POSS content on properties

Abstract

Keywords

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POSS-based poly(aryl ether sulfone)s random terpolymer linked POSS to the main chain: effect of chemical structure and POSS content on properties

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