Preparation and solid state characterization of 1,2,3,5-diselenadiazolyl [HCN2Se2]

A. Wallace Cordes; S. H. Glarum; R. C. Haddon; Randal Hallford; R. G. Hicks; D. K. Kennepohl; Richard T. Oakley; T.M. Palstra; S. R. Scott

doi:10.1039/C39920001265

Preparation and solid state characterization of 1,2,3,5-diselenadiazolyl [HCN2Se2]

A. Wallace Cordes, S. H. Glarum, R. C. Haddon, Randal Hallford, R. G. Hicks, D. K. Kennepohl, Richard T. Oakley, T.M. Palstra, S. R. Scott

University of Twente

Research output: Contribution to journal › Article › Academic › peer-review

26 Citations (Scopus)

111 Downloads (Pure)

Abstract

The reaction of N,N,N′-tris(trimethylsilyl)formamidine with SeCl2 affords 1,2,3,5-diselenadiazolium chloride, which can be reduced with triphenylantimony to the corresponding diselenadiazolyl radical [HCN2Se2]˙; the solid state structure and conductivity of the dimer [HCN2Se2]2 are reported.

Original language	English
Pages (from-to)	1265-1266
Journal	Journal of the Chemical Society. Chemical communications
Volume	1992
Issue number	17
DOIs	https://doi.org/10.1039/C39920001265
Publication status	Published - 1992

Access to Document

10.1039/C39920001265

rto_117Final published version, 246 KB

Cite this

@article{a3c1eb7d2bf941bfb56d66452258562d,

title = "Preparation and solid state characterization of 1,2,3,5-diselenadiazolyl [HCN2Se2]",

abstract = "The reaction of N,N,N′-tris(trimethylsilyl)formamidine with SeCl2 affords 1,2,3,5-diselenadiazolium chloride, which can be reduced with triphenylantimony to the corresponding diselenadiazolyl radical [HCN2Se2]˙; the solid state structure and conductivity of the dimer [HCN2Se2]2 are reported.",

author = "Cordes, {A. Wallace} and Glarum, {S. H.} and Haddon, {R. C.} and Randal Hallford and Hicks, {R. G.} and Kennepohl, {D. K.} and Oakley, {Richard T.} and T.M. Palstra and Scott, {S. R.}",

year = "1992",

doi = "10.1039/C39920001265",

language = "English",

volume = "1992",

pages = "1265--1266",

journal = "Chemical communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "17",

}

TY - JOUR

T1 - Preparation and solid state characterization of 1,2,3,5-diselenadiazolyl [HCN2Se2]

AU - Cordes, A. Wallace

AU - Glarum, S. H.

AU - Haddon, R. C.

AU - Hallford, Randal

AU - Hicks, R. G.

AU - Kennepohl, D. K.

AU - Oakley, Richard T.

AU - Palstra, T.M.

AU - Scott, S. R.

PY - 1992

Y1 - 1992

N2 - The reaction of N,N,N′-tris(trimethylsilyl)formamidine with SeCl2 affords 1,2,3,5-diselenadiazolium chloride, which can be reduced with triphenylantimony to the corresponding diselenadiazolyl radical [HCN2Se2]˙; the solid state structure and conductivity of the dimer [HCN2Se2]2 are reported.

AB - The reaction of N,N,N′-tris(trimethylsilyl)formamidine with SeCl2 affords 1,2,3,5-diselenadiazolium chloride, which can be reduced with triphenylantimony to the corresponding diselenadiazolyl radical [HCN2Se2]˙; the solid state structure and conductivity of the dimer [HCN2Se2]2 are reported.

U2 - 10.1039/C39920001265

DO - 10.1039/C39920001265

M3 - Article

VL - 1992

SP - 1265

EP - 1266

JO - Chemical communications

JF - Chemical communications

SN - 1359-7345

IS - 17

ER -

Preparation and solid state characterization of 1,2,3,5-diselenadiazolyl [HCN2Se2]

Abstract

Access to Document

Fingerprint

Cite this