Probing buried carbon nanotubes within polymer-nanotube composite matrices by Atomic Force Microscopy

In Yee Phang, Tianxi Liu, Wei-De Zhang, Holger Schönherr, Gyula J. Vancso

Research output: Contribution to journalArticleAcademicpeer-review

22 Citations (Scopus)

Abstract

Multi-walled carbon nanotubes (MW-CNT) inside a polyamide-6 (PA6)–MW-CNT composite were visualized by atomic force microscopy (i) in a field-assisted intermittent contact and (ii) in the tunneling (TUNA) mode. Individual buried MW-CNTs were clearly discerned within the PA6 matrix. An average diameter of 33 ± 5 nm of the MW-CNTs was determined based on field-assisted intermittent contact mode AFM images, which is consistent with the expected size of PA6-coated MW-CNTs. Single well dispersed MW-CNTs that are located in the sub-surface region of the composite were also observed in the TUNA mode. These new AFM approaches circumvent the tedious sample preparation based on ultramicrotoming required for high resolution electron microscopy studies to obtain “in-depth” morphological information and hence are expected to facilitate the analysis of CNT-based and other nanocomposites in the future.
Original languageUndefined
Pages (from-to)4136-4142
Number of pages7
JournalEuropean polymer journal
Volume43
Issue number10
DOIs
Publication statusPublished - 2007

Keywords

  • Nylon-6
  • TUNA mode
  • Conducting mode
  • Atomic Force Microscopy
  • IR-72079
  • Carbon nanotube composites
  • METIS-243271

Cite this

Phang, In Yee ; Liu, Tianxi ; Zhang, Wei-De ; Schönherr, Holger ; Vancso, Gyula J. / Probing buried carbon nanotubes within polymer-nanotube composite matrices by Atomic Force Microscopy. In: European polymer journal. 2007 ; Vol. 43, No. 10. pp. 4136-4142.
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abstract = "Multi-walled carbon nanotubes (MW-CNT) inside a polyamide-6 (PA6)–MW-CNT composite were visualized by atomic force microscopy (i) in a field-assisted intermittent contact and (ii) in the tunneling (TUNA) mode. Individual buried MW-CNTs were clearly discerned within the PA6 matrix. An average diameter of 33 ± 5 nm of the MW-CNTs was determined based on field-assisted intermittent contact mode AFM images, which is consistent with the expected size of PA6-coated MW-CNTs. Single well dispersed MW-CNTs that are located in the sub-surface region of the composite were also observed in the TUNA mode. These new AFM approaches circumvent the tedious sample preparation based on ultramicrotoming required for high resolution electron microscopy studies to obtain “in-depth” morphological information and hence are expected to facilitate the analysis of CNT-based and other nanocomposites in the future.",
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Probing buried carbon nanotubes within polymer-nanotube composite matrices by Atomic Force Microscopy. / Phang, In Yee; Liu, Tianxi; Zhang, Wei-De; Schönherr, Holger; Vancso, Gyula J.

In: European polymer journal, Vol. 43, No. 10, 2007, p. 4136-4142.

Research output: Contribution to journalArticleAcademicpeer-review

TY - JOUR

T1 - Probing buried carbon nanotubes within polymer-nanotube composite matrices by Atomic Force Microscopy

AU - Phang, In Yee

AU - Liu, Tianxi

AU - Zhang, Wei-De

AU - Schönherr, Holger

AU - Vancso, Gyula J.

PY - 2007

Y1 - 2007

N2 - Multi-walled carbon nanotubes (MW-CNT) inside a polyamide-6 (PA6)–MW-CNT composite were visualized by atomic force microscopy (i) in a field-assisted intermittent contact and (ii) in the tunneling (TUNA) mode. Individual buried MW-CNTs were clearly discerned within the PA6 matrix. An average diameter of 33 ± 5 nm of the MW-CNTs was determined based on field-assisted intermittent contact mode AFM images, which is consistent with the expected size of PA6-coated MW-CNTs. Single well dispersed MW-CNTs that are located in the sub-surface region of the composite were also observed in the TUNA mode. These new AFM approaches circumvent the tedious sample preparation based on ultramicrotoming required for high resolution electron microscopy studies to obtain “in-depth” morphological information and hence are expected to facilitate the analysis of CNT-based and other nanocomposites in the future.

AB - Multi-walled carbon nanotubes (MW-CNT) inside a polyamide-6 (PA6)–MW-CNT composite were visualized by atomic force microscopy (i) in a field-assisted intermittent contact and (ii) in the tunneling (TUNA) mode. Individual buried MW-CNTs were clearly discerned within the PA6 matrix. An average diameter of 33 ± 5 nm of the MW-CNTs was determined based on field-assisted intermittent contact mode AFM images, which is consistent with the expected size of PA6-coated MW-CNTs. Single well dispersed MW-CNTs that are located in the sub-surface region of the composite were also observed in the TUNA mode. These new AFM approaches circumvent the tedious sample preparation based on ultramicrotoming required for high resolution electron microscopy studies to obtain “in-depth” morphological information and hence are expected to facilitate the analysis of CNT-based and other nanocomposites in the future.

KW - Nylon-6

KW - TUNA mode

KW - Conducting mode

KW - Atomic Force Microscopy

KW - IR-72079

KW - Carbon nanotube composites

KW - METIS-243271

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SN - 0014-3057

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