Abstract
| Original language | Undefined |
|---|---|
| Pages (from-to) | 9862-9870 |
| Journal | Industrial and engineering chemistry research |
| Volume | 47 |
| Issue number | 24 |
| DOIs | |
| Publication status | Published - 2008 |
Keywords
- IR-67397
- METIS-252150
Cite this
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Reaction from dimethyl carbonate (DMC) to diphenyl carbonate (DPC). Part 2: Kinetics of the reactions from DMC via Methyl Phenyl Carbonate (MPC) to DPC. / Haubrock, J.; Wermink, W.; Versteeg, Geert; Kooijman, H.A.; Taylor, R.; van Sint Annaland, M.; Hogendoorn, Kees.
In: Industrial and engineering chemistry research, Vol. 47, No. 24, 2008, p. 9862-9870.Research output: Contribution to journal › Article › Academic › peer-review
TY - JOUR
T1 - Reaction from dimethyl carbonate (DMC) to diphenyl carbonate (DPC). Part 2: Kinetics of the reactions from DMC via Methyl Phenyl Carbonate (MPC) to DPC
AU - Haubrock, J.
AU - Wermink, W.
AU - Versteeg, Geert
AU - Kooijman, H.A.
AU - Taylor, R.
AU - van Sint Annaland, M.
AU - Hogendoorn, Kees
PY - 2008
Y1 - 2008
N2 - The kinetics of the reaction of dimethyl carbonate (DMC) and phenol to methyl phenyl carbonate (MPC) and the subsequent disproportion and transesterification reaction of methyl phenyl carbonate (MPC) to diphenyl carbonate (DPC) have been studied. Experiments were carried out in a closed batch reactor in the temperature range from 160 to 200 °C for initial reactant ratios of DMC/phenol from 0.25 to 3 and varying catalyst (titanium-(n-butoxide)) concentrations. The concept of a closed, ideally stirred, isothermal batch reactor incorporating an activity based reaction rate model has been used to fit kinetic parameters to the experimental data taking into account the catalyst concentration, the initial reactant ratio DMC/phenol and the temperature.
AB - The kinetics of the reaction of dimethyl carbonate (DMC) and phenol to methyl phenyl carbonate (MPC) and the subsequent disproportion and transesterification reaction of methyl phenyl carbonate (MPC) to diphenyl carbonate (DPC) have been studied. Experiments were carried out in a closed batch reactor in the temperature range from 160 to 200 °C for initial reactant ratios of DMC/phenol from 0.25 to 3 and varying catalyst (titanium-(n-butoxide)) concentrations. The concept of a closed, ideally stirred, isothermal batch reactor incorporating an activity based reaction rate model has been used to fit kinetic parameters to the experimental data taking into account the catalyst concentration, the initial reactant ratio DMC/phenol and the temperature.
KW - IR-67397
KW - METIS-252150
U2 - 10.1021/ie071176d
DO - 10.1021/ie071176d
M3 - Article
VL - 47
SP - 9862
EP - 9870
JO - Industrial and engineering chemistry research
JF - Industrial and engineering chemistry research
SN - 0888-5885
IS - 24
ER -