Reaction from dimethyl carbonate (DMC) to diphenyl carbonate (DPC). Part 2: Kinetics of the reactions from DMC via Methyl Phenyl Carbonate (MPC) to DPC

J. Haubrock, W. Wermink, Geert Versteeg, H.A. Kooijman, R. Taylor, M. van Sint Annaland, Kees Hogendoorn

Research output: Contribution to journalArticleAcademicpeer-review

27 Citations (Scopus)

Abstract

The kinetics of the reaction of dimethyl carbonate (DMC) and phenol to methyl phenyl carbonate (MPC) and the subsequent disproportion and transesterification reaction of methyl phenyl carbonate (MPC) to diphenyl carbonate (DPC) have been studied. Experiments were carried out in a closed batch reactor in the temperature range from 160 to 200 °C for initial reactant ratios of DMC/phenol from 0.25 to 3 and varying catalyst (titanium-(n-butoxide)) concentrations. The concept of a closed, ideally stirred, isothermal batch reactor incorporating an activity based reaction rate model has been used to fit kinetic parameters to the experimental data taking into account the catalyst concentration, the initial reactant ratio DMC/phenol and the temperature.
Original languageUndefined
Pages (from-to)9862-9870
JournalIndustrial and engineering chemistry research
Volume47
Issue number24
DOIs
Publication statusPublished - 2008

Keywords

  • IR-67397
  • METIS-252150

Cite this

Haubrock, J. ; Wermink, W. ; Versteeg, Geert ; Kooijman, H.A. ; Taylor, R. ; van Sint Annaland, M. ; Hogendoorn, Kees. / Reaction from dimethyl carbonate (DMC) to diphenyl carbonate (DPC). Part 2: Kinetics of the reactions from DMC via Methyl Phenyl Carbonate (MPC) to DPC. In: Industrial and engineering chemistry research. 2008 ; Vol. 47, No. 24. pp. 9862-9870.
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abstract = "The kinetics of the reaction of dimethyl carbonate (DMC) and phenol to methyl phenyl carbonate (MPC) and the subsequent disproportion and transesterification reaction of methyl phenyl carbonate (MPC) to diphenyl carbonate (DPC) have been studied. Experiments were carried out in a closed batch reactor in the temperature range from 160 to 200 °C for initial reactant ratios of DMC/phenol from 0.25 to 3 and varying catalyst (titanium-(n-butoxide)) concentrations. The concept of a closed, ideally stirred, isothermal batch reactor incorporating an activity based reaction rate model has been used to fit kinetic parameters to the experimental data taking into account the catalyst concentration, the initial reactant ratio DMC/phenol and the temperature.",
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year = "2008",
doi = "10.1021/ie071176d",
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Reaction from dimethyl carbonate (DMC) to diphenyl carbonate (DPC). Part 2: Kinetics of the reactions from DMC via Methyl Phenyl Carbonate (MPC) to DPC. / Haubrock, J.; Wermink, W.; Versteeg, Geert; Kooijman, H.A.; Taylor, R.; van Sint Annaland, M.; Hogendoorn, Kees.

In: Industrial and engineering chemistry research, Vol. 47, No. 24, 2008, p. 9862-9870.

Research output: Contribution to journalArticleAcademicpeer-review

TY - JOUR

T1 - Reaction from dimethyl carbonate (DMC) to diphenyl carbonate (DPC). Part 2: Kinetics of the reactions from DMC via Methyl Phenyl Carbonate (MPC) to DPC

AU - Haubrock, J.

AU - Wermink, W.

AU - Versteeg, Geert

AU - Kooijman, H.A.

AU - Taylor, R.

AU - van Sint Annaland, M.

AU - Hogendoorn, Kees

PY - 2008

Y1 - 2008

N2 - The kinetics of the reaction of dimethyl carbonate (DMC) and phenol to methyl phenyl carbonate (MPC) and the subsequent disproportion and transesterification reaction of methyl phenyl carbonate (MPC) to diphenyl carbonate (DPC) have been studied. Experiments were carried out in a closed batch reactor in the temperature range from 160 to 200 °C for initial reactant ratios of DMC/phenol from 0.25 to 3 and varying catalyst (titanium-(n-butoxide)) concentrations. The concept of a closed, ideally stirred, isothermal batch reactor incorporating an activity based reaction rate model has been used to fit kinetic parameters to the experimental data taking into account the catalyst concentration, the initial reactant ratio DMC/phenol and the temperature.

AB - The kinetics of the reaction of dimethyl carbonate (DMC) and phenol to methyl phenyl carbonate (MPC) and the subsequent disproportion and transesterification reaction of methyl phenyl carbonate (MPC) to diphenyl carbonate (DPC) have been studied. Experiments were carried out in a closed batch reactor in the temperature range from 160 to 200 °C for initial reactant ratios of DMC/phenol from 0.25 to 3 and varying catalyst (titanium-(n-butoxide)) concentrations. The concept of a closed, ideally stirred, isothermal batch reactor incorporating an activity based reaction rate model has been used to fit kinetic parameters to the experimental data taking into account the catalyst concentration, the initial reactant ratio DMC/phenol and the temperature.

KW - IR-67397

KW - METIS-252150

U2 - 10.1021/ie071176d

DO - 10.1021/ie071176d

M3 - Article

VL - 47

SP - 9862

EP - 9870

JO - Industrial and engineering chemistry research

JF - Industrial and engineering chemistry research

SN - 0888-5885

IS - 24

ER -