Redox-active Crosslinkable Poly(ionic liquid)s

Xiaofeng Sui; Mark A. Hempenius; Gyula J. Vancso

doi:10.1021/ja211662k

Redox-active Crosslinkable Poly(ionic liquid)s

Xiaofeng Sui, Mark A. Hempenius, Gyula J. Vancso

Research output: Contribution to journal › Article › Academic › peer-review

86 Citations (Scopus)

Abstract

The synthesis of a new class of cross-linkable redox-responsive poly(ferrocenylsilane)-based poly(ionic liquid)s (PFS-PILs) is reported. PFS-PILs self-cross-link at low concentrations into nanogels or form macroscopic hydrogel networks at higher concentrations. PFS-PILs proved to be efficient dispersants in the microemulsion polymerization of methyl methacrylate, producing stable PFS–poly(methyl methacrylate) latex suspensions

Original language	English
Pages (from-to)	4023-4025
Number of pages	3
Journal	Journal of the American Chemical Society
Volume	134
Issue number	9
DOIs	https://doi.org/10.1021/ja211662k
Publication status	Published - 2012

Keywords

METIS-289595
IR-84745

Access to Document

10.1021/ja211662k

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title = "Redox-active Crosslinkable Poly(ionic liquid)s",

abstract = "The synthesis of a new class of cross-linkable redox-responsive poly(ferrocenylsilane)-based poly(ionic liquid)s (PFS-PILs) is reported. PFS-PILs self-cross-link at low concentrations into nanogels or form macroscopic hydrogel networks at higher concentrations. PFS-PILs proved to be efficient dispersants in the microemulsion polymerization of methyl methacrylate, producing stable PFS–poly(methyl methacrylate) latex suspensions",

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AU - Sui, Xiaofeng

AU - Hempenius, Mark A.

AU - Vancso, Gyula J.

PY - 2012

Y1 - 2012

N2 - The synthesis of a new class of cross-linkable redox-responsive poly(ferrocenylsilane)-based poly(ionic liquid)s (PFS-PILs) is reported. PFS-PILs self-cross-link at low concentrations into nanogels or form macroscopic hydrogel networks at higher concentrations. PFS-PILs proved to be efficient dispersants in the microemulsion polymerization of methyl methacrylate, producing stable PFS–poly(methyl methacrylate) latex suspensions

AB - The synthesis of a new class of cross-linkable redox-responsive poly(ferrocenylsilane)-based poly(ionic liquid)s (PFS-PILs) is reported. PFS-PILs self-cross-link at low concentrations into nanogels or form macroscopic hydrogel networks at higher concentrations. PFS-PILs proved to be efficient dispersants in the microemulsion polymerization of methyl methacrylate, producing stable PFS–poly(methyl methacrylate) latex suspensions

KW - METIS-289595

KW - IR-84745

U2 - 10.1021/ja211662k

DO - 10.1021/ja211662k

M3 - Article

VL - 134

SP - 4023

EP - 4025

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

SN - 0002-7863

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