Redox-responsive organometallic microgel particles prepared from poly(ferrocenylsilane)s generated using microfluidics

Xiaofeng Sui; Lingling Shui; Jin Cui; Yanbo Xie; Jing Song; Albert van den Berg; Mark A. Hempenius; G. Julius Vancso

doi:10.1039/C3CC49501A

Redox-responsive organometallic microgel particles prepared from poly(ferrocenylsilane)s generated using microfluidics

Xiaofeng Sui, Lingling Shui, Jin Cui, Yanbo Xie, Jing Song, Albert van den Berg, Mark A. Hempenius, G. Julius Vancso

Research output: Contribution to journal › Article › Academic › peer-review

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Abstract

We describe a novel and versatile method for the fabrication of poly(ferrocenylsilane) (PFS) based microspheres using microfluidics. Cross-linked microgel particles were obtained by UV-induced crosslinking of precursor droplets. By variations in the substitution of the silane units of PFS, organogel as well as hydrogel particles were prepared. Applications of these redox active microspheres to form in situ Ag nanoparticles, as well as loading and release of guest molecules were demonstrated.

Original language	English
Pages (from-to)	3058-3060
Number of pages	3
Journal	Chemical communications
Volume	50
Issue number	23
DOIs	https://doi.org/10.1039/C3CC49501A
Publication status	Published - 2014

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abstract = "We describe a novel and versatile method for the fabrication of poly(ferrocenylsilane) (PFS) based microspheres using microfluidics. Cross-linked microgel particles were obtained by UV-induced crosslinking of precursor droplets. By variations in the substitution of the silane units of PFS, organogel as well as hydrogel particles were prepared. Applications of these redox active microspheres to form in situ Ag nanoparticles, as well as loading and release of guest molecules were demonstrated.",

author = "Xiaofeng Sui and Lingling Shui and Jin Cui and Yanbo Xie and Jing Song and {van den Berg}, Albert and Hempenius, {Mark A.} and Vancso, {G. Julius}",

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AU - Sui, Xiaofeng

AU - Shui, Lingling

AU - Cui, Jin

AU - Xie, Yanbo

AU - Song, Jing

AU - van den Berg, Albert

AU - Hempenius, Mark A.

AU - Vancso, G. Julius

N1 - 10.1039/c3cc49501a

PY - 2014

Y1 - 2014

N2 - We describe a novel and versatile method for the fabrication of poly(ferrocenylsilane) (PFS) based microspheres using microfluidics. Cross-linked microgel particles were obtained by UV-induced crosslinking of precursor droplets. By variations in the substitution of the silane units of PFS, organogel as well as hydrogel particles were prepared. Applications of these redox active microspheres to form in situ Ag nanoparticles, as well as loading and release of guest molecules were demonstrated.

AB - We describe a novel and versatile method for the fabrication of poly(ferrocenylsilane) (PFS) based microspheres using microfluidics. Cross-linked microgel particles were obtained by UV-induced crosslinking of precursor droplets. By variations in the substitution of the silane units of PFS, organogel as well as hydrogel particles were prepared. Applications of these redox active microspheres to form in situ Ag nanoparticles, as well as loading and release of guest molecules were demonstrated.

U2 - 10.1039/C3CC49501A

DO - 10.1039/C3CC49501A

M3 - Article

SN - 1359-7345

VL - 50

SP - 3058

EP - 3060

JO - Chemical communications

JF - Chemical communications

IS - 23

ER -

Redox-responsive organometallic microgel particles prepared from poly(ferrocenylsilane)s generated using microfluidics

Abstract

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