Redox-responsive organometallic microgel particles prepared from poly(ferrocenylsilane)s generated using microfluidics

Xiaofeng Sui, Xiaofeng Sui, Lingling Shui, Lingling Shui, Jin Cui, Jin Cui, Yanbo Xie, Jing Song, Albert van den Berg, Mark A. Hempenius, Gyula J. Vancso

Research output: Contribution to journalArticleAcademicpeer-review

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Abstract

We describe a novel and versatile method for the fabrication of poly(ferrocenylsilane) (PFS) based microspheres using microfluidics. Cross-linked microgel particles were obtained by UV-induced crosslinking of precursor droplets. By variations in the substitution of the silane units of PFS, organogel as well as hydrogel particles were prepared. Applications of these redox active microspheres to form in situ Ag nanoparticles, as well as loading and release of guest molecules were demonstrated.
Original languageUndefined
Pages (from-to)3058-3060
Number of pages3
JournalChemical communications
Volume50
Issue number23
DOIs
Publication statusPublished - 2014

Keywords

  • IR-90572
  • EWI-24684
  • METIS-304077

Cite this

Sui, Xiaofeng ; Sui, Xiaofeng ; Shui, Lingling ; Shui, Lingling ; Cui, Jin ; Cui, Jin ; Xie, Yanbo ; Song, Jing ; van den Berg, Albert ; Hempenius, Mark A. ; Vancso, Gyula J. / Redox-responsive organometallic microgel particles prepared from poly(ferrocenylsilane)s generated using microfluidics. In: Chemical communications. 2014 ; Vol. 50, No. 23. pp. 3058-3060.
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author = "Xiaofeng Sui and Xiaofeng Sui and Lingling Shui and Lingling Shui and Jin Cui and Jin Cui and Yanbo Xie and Jing Song and {van den Berg}, Albert and Hempenius, {Mark A.} and Vancso, {Gyula J.}",
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volume = "50",
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Redox-responsive organometallic microgel particles prepared from poly(ferrocenylsilane)s generated using microfluidics. / Sui, Xiaofeng; Sui, Xiaofeng; Shui, Lingling; Shui, Lingling; Cui, Jin; Cui, Jin; Xie, Yanbo; Song, Jing; van den Berg, Albert; Hempenius, Mark A.; Vancso, Gyula J.

In: Chemical communications, Vol. 50, No. 23, 2014, p. 3058-3060.

Research output: Contribution to journalArticleAcademicpeer-review

TY - JOUR

T1 - Redox-responsive organometallic microgel particles prepared from poly(ferrocenylsilane)s generated using microfluidics

AU - Sui, Xiaofeng

AU - Sui, Xiaofeng

AU - Shui, Lingling

AU - Shui, Lingling

AU - Cui, Jin

AU - Cui, Jin

AU - Xie, Yanbo

AU - Song, Jing

AU - van den Berg, Albert

AU - Hempenius, Mark A.

AU - Vancso, Gyula J.

N1 - 10.1039/c3cc49501a

PY - 2014

Y1 - 2014

N2 - We describe a novel and versatile method for the fabrication of poly(ferrocenylsilane) (PFS) based microspheres using microfluidics. Cross-linked microgel particles were obtained by UV-induced crosslinking of precursor droplets. By variations in the substitution of the silane units of PFS, organogel as well as hydrogel particles were prepared. Applications of these redox active microspheres to form in situ Ag nanoparticles, as well as loading and release of guest molecules were demonstrated.

AB - We describe a novel and versatile method for the fabrication of poly(ferrocenylsilane) (PFS) based microspheres using microfluidics. Cross-linked microgel particles were obtained by UV-induced crosslinking of precursor droplets. By variations in the substitution of the silane units of PFS, organogel as well as hydrogel particles were prepared. Applications of these redox active microspheres to form in situ Ag nanoparticles, as well as loading and release of guest molecules were demonstrated.

KW - IR-90572

KW - EWI-24684

KW - METIS-304077

U2 - 10.1039/C3CC49501A

DO - 10.1039/C3CC49501A

M3 - Article

VL - 50

SP - 3058

EP - 3060

JO - Chemical communications

JF - Chemical communications

SN - 1359-7345

IS - 23

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