Remarkable acidity independent actinide extraction with a both-side diglycolamide-functionalized calix[4]arene

Prasanta K. Mohapatra; Arijit Sengupta; Mudassir Iqbal; Jurriaan Huskens; Shrikant V. Godbole; Willem Verboom

doi:10.1039/C3DT50557J

Remarkable acidity independent actinide extraction with a both-side diglycolamide-functionalized calix[4]arene

Prasanta K. Mohapatra
, Arijit Sengupta
, Mudassir Iqbal
, Jurriaan Huskens
, Shrikant V. Godbole
, Willem Verboom

Research output: Contribution to journal › Article › Academic › peer-review

45 Citations (Scopus)

4 Downloads (Pure)

Abstract

A novel solvent system containing a newly synthesized both-side diglycolamide-functionalized calix[4]arene (L-I) in a room temperature ionic liquid showed highly efficient extraction of actinides and a remarkable acid concentration independent extraction of trivalent actinide ion, Am3+ suggesting its possible use for high level radioactive waste remediation. The nature of the complexes was ascertained by slope analysis, luminescence spectroscopic investigations and from the thermodynamic parameters. The sustainability of the solvent system for long term applications was also investigated

Original language	English
Pages (from-to)	8558-8562
Number of pages	5
Journal	Dalton transactions
Volume	42
Issue number	24
DOIs	https://doi.org/10.1039/C3DT50557J
Publication status	Published - 2013

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This output contributes to the following UN Sustainable Development Goals (SDGs)

SDG 12 Responsible Consumption and Production

Keywords

2020 OA procedure

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10.1039/C3DT50557J

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abstract = "A novel solvent system containing a newly synthesized both-side diglycolamide-functionalized calix[4]arene (L-I) in a room temperature ionic liquid showed highly efficient extraction of actinides and a remarkable acid concentration independent extraction of trivalent actinide ion, Am3+ suggesting its possible use for high level radioactive waste remediation. The nature of the complexes was ascertained by slope analysis, luminescence spectroscopic investigations and from the thermodynamic parameters. The sustainability of the solvent system for long term applications was also investigated",

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AU - Mohapatra, Prasanta K.

AU - Sengupta, Arijit

AU - Iqbal, Mudassir

AU - Huskens, Jurriaan

AU - Godbole, Shrikant V.

AU - Verboom, Willem

PY - 2013

Y1 - 2013

N2 - A novel solvent system containing a newly synthesized both-side diglycolamide-functionalized calix[4]arene (L-I) in a room temperature ionic liquid showed highly efficient extraction of actinides and a remarkable acid concentration independent extraction of trivalent actinide ion, Am3+ suggesting its possible use for high level radioactive waste remediation. The nature of the complexes was ascertained by slope analysis, luminescence spectroscopic investigations and from the thermodynamic parameters. The sustainability of the solvent system for long term applications was also investigated

AB - A novel solvent system containing a newly synthesized both-side diglycolamide-functionalized calix[4]arene (L-I) in a room temperature ionic liquid showed highly efficient extraction of actinides and a remarkable acid concentration independent extraction of trivalent actinide ion, Am3+ suggesting its possible use for high level radioactive waste remediation. The nature of the complexes was ascertained by slope analysis, luminescence spectroscopic investigations and from the thermodynamic parameters. The sustainability of the solvent system for long term applications was also investigated

KW - 2020 OA procedure

U2 - 10.1039/C3DT50557J

DO - 10.1039/C3DT50557J

M3 - Article

SN - 1477-9226

VL - 42

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EP - 8562

JO - Dalton transactions

JF - Dalton transactions

IS - 24

ER -

Remarkable acidity independent actinide extraction with a both-side diglycolamide-functionalized calix[4]arene

Abstract

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