Role of electronic localization and charge-vibrational coupling in resonant photoelectron spectra of polymers: Application to poly(para-phenylenevinylene)

R. Friedlein; S. L. Sorensen; A. Baev; F. Gel’mukhanov; J. Birgerson; A. Crispin; M. P. De Jong; W. Osikowicz; C. Murphy; H. Ågren; W. R. Salaneck

doi:10.1103/PhysRevB.69.125204

Role of electronic localization and charge-vibrational coupling in resonant photoelectron spectra of polymers: Application to poly(para-phenylenevinylene)

R. Friedlein, S. L. Sorensen, A. Baev, F. Gel’mukhanov, J. Birgerson, A. Crispin, M. P. De Jong, W. Osikowicz, C. Murphy, H. Ågren, W. R. Salaneck

Research output: Contribution to journal › Article › Academic › peer-review

17 Citations (Scopus)

Abstract

A combination of x-ray absorption and resonant photoemission (RPE) spectroscopy has been used to study the electronic structure of the one-dimensional conjugated polymer poly(para-phenylenevinylene) in nonordered (as prepared) thin films. The dispersion of RPE features for the decay to localized and delocalized bands are qualitatively different. A theory for band dispersion of RPE in polymers is given, showing the important roles of electronic state localization and vibrational (phonon) excitations for the character of the dispersion.

Original language	English
Journal	Physical Review B - Condensed Matter and Materials Physics
Volume	69
Issue number	12
DOIs	https://doi.org/10.1103/PhysRevB.69.125204
Publication status	Published - 9 Mar 2004
Externally published	Yes

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10.1103/PhysRevB.69.125204

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Friedlein, R., Sorensen, S. L., Baev, A., Gel’mukhanov, F., Birgerson, J., Crispin, A., De Jong, M. P., Osikowicz, W., Murphy, C., Ågren, H., & Salaneck, W. R. (2004). Role of electronic localization and charge-vibrational coupling in resonant photoelectron spectra of polymers: Application to poly(para-phenylenevinylene). Physical Review B - Condensed Matter and Materials Physics, 69(12). https://doi.org/10.1103/PhysRevB.69.125204

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abstract = "A combination of x-ray absorption and resonant photoemission (RPE) spectroscopy has been used to study the electronic structure of the one-dimensional conjugated polymer poly(para-phenylenevinylene) in nonordered (as prepared) thin films. The dispersion of RPE features for the decay to localized and delocalized bands are qualitatively different. A theory for band dispersion of RPE in polymers is given, showing the important roles of electronic state localization and vibrational (phonon) excitations for the character of the dispersion.",

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month = mar,

day = "9",

doi = "10.1103/PhysRevB.69.125204",

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Friedlein, R, Sorensen, SL, Baev, A, Gel’mukhanov, F, Birgerson, J, Crispin, A, De Jong, MP, Osikowicz, W, Murphy, C, Ågren, H & Salaneck, WR 2004, 'Role of electronic localization and charge-vibrational coupling in resonant photoelectron spectra of polymers: Application to poly(para-phenylenevinylene)', Physical Review B - Condensed Matter and Materials Physics, vol. 69, no. 12. https://doi.org/10.1103/PhysRevB.69.125204

Role of electronic localization and charge-vibrational coupling in resonant photoelectron spectra of polymers: Application to poly(para-phenylenevinylene). / Friedlein, R.; Sorensen, S. L.; Baev, A. et al.
In: Physical Review B - Condensed Matter and Materials Physics, Vol. 69, No. 12, 09.03.2004.

Research output: Contribution to journal › Article › Academic › peer-review

TY - JOUR

T1 - Role of electronic localization and charge-vibrational coupling in resonant photoelectron spectra of polymers

T2 - Application to poly(para-phenylenevinylene)

AU - Friedlein, R.

AU - Sorensen, S. L.

AU - Baev, A.

AU - Gel’mukhanov, F.

AU - Birgerson, J.

AU - Crispin, A.

AU - De Jong, M. P.

AU - Osikowicz, W.

AU - Murphy, C.

AU - Ågren, H.

AU - Salaneck, W. R.

PY - 2004/3/9

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N2 - A combination of x-ray absorption and resonant photoemission (RPE) spectroscopy has been used to study the electronic structure of the one-dimensional conjugated polymer poly(para-phenylenevinylene) in nonordered (as prepared) thin films. The dispersion of RPE features for the decay to localized and delocalized bands are qualitatively different. A theory for band dispersion of RPE in polymers is given, showing the important roles of electronic state localization and vibrational (phonon) excitations for the character of the dispersion.

AB - A combination of x-ray absorption and resonant photoemission (RPE) spectroscopy has been used to study the electronic structure of the one-dimensional conjugated polymer poly(para-phenylenevinylene) in nonordered (as prepared) thin films. The dispersion of RPE features for the decay to localized and delocalized bands are qualitatively different. A theory for band dispersion of RPE in polymers is given, showing the important roles of electronic state localization and vibrational (phonon) excitations for the character of the dispersion.

KW - n/a OA procedure

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U2 - 10.1103/PhysRevB.69.125204

DO - 10.1103/PhysRevB.69.125204

M3 - Article

AN - SCOPUS:2342437341

SN - 1098-0121

VL - 69

JO - Physical Review B - Condensed Matter and Materials Physics

JF - Physical Review B - Condensed Matter and Materials Physics

IS - 12

ER -

Role of electronic localization and charge-vibrational coupling in resonant photoelectron spectra of polymers: Application to poly(para-phenylenevinylene)

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