Room temperature excitation spectroscopy of single quantum dots

Christian Blum, Frank Schleifenbaum, M.H.W. Stopel, Sebastien Peter, Marcus Sackrow, Vinod Subramaniam, Alfred J. Meixner

Research output: Contribution to journalArticleAcademicpeer-review

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Abstract

We report a single molecule detection scheme to investigate excitation spectra of single emitters at room temperature. We demonstrate the potential of single emitter photoluminescence excitation spectroscopy by recording excitation spectra of single CdSe nanocrystals over a wide spectral range of 100 nm. The spectra exhibit emission intermittency, characteristic of single emitters. We observe large variations in the spectra close to the band edge, which represent the individual heterogeneity of the observed quantum dots. We also find specific excitation wavelengths for which the single quantum dots analyzed show an increased propensity for a transition to a long-lived dark state. We expect that the additional capability of recording excitation spectra at room temperature from single emitters will enable insights into the photophysics of emitters that so far have remained inaccessible.
Original languageUndefined
Pages (from-to)516-524
Number of pages9
JournalBeilstein journal of nanotechnology
Volume2
DOIs
Publication statusPublished - 2011

Keywords

  • METIS-280828
  • IR-104424

Cite this

Blum, C., Schleifenbaum, F., Stopel, M. H. W., Peter, S., Sackrow, M., Subramaniam, V., & Meixner, A. J. (2011). Room temperature excitation spectroscopy of single quantum dots. Beilstein journal of nanotechnology, 2, 516-524. https://doi.org/10.3762/bjnano.2.56
Blum, Christian ; Schleifenbaum, Frank ; Stopel, M.H.W. ; Peter, Sebastien ; Sackrow, Marcus ; Subramaniam, Vinod ; Meixner, Alfred J. / Room temperature excitation spectroscopy of single quantum dots. In: Beilstein journal of nanotechnology. 2011 ; Vol. 2. pp. 516-524.
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Blum, C, Schleifenbaum, F, Stopel, MHW, Peter, S, Sackrow, M, Subramaniam, V & Meixner, AJ 2011, 'Room temperature excitation spectroscopy of single quantum dots', Beilstein journal of nanotechnology, vol. 2, pp. 516-524. https://doi.org/10.3762/bjnano.2.56

Room temperature excitation spectroscopy of single quantum dots. / Blum, Christian; Schleifenbaum, Frank; Stopel, M.H.W.; Peter, Sebastien; Sackrow, Marcus; Subramaniam, Vinod; Meixner, Alfred J.

In: Beilstein journal of nanotechnology, Vol. 2, 2011, p. 516-524.

Research output: Contribution to journalArticleAcademicpeer-review

TY - JOUR

T1 - Room temperature excitation spectroscopy of single quantum dots

AU - Blum, Christian

AU - Schleifenbaum, Frank

AU - Stopel, M.H.W.

AU - Peter, Sebastien

AU - Sackrow, Marcus

AU - Subramaniam, Vinod

AU - Meixner, Alfred J.

N1 - Open access

PY - 2011

Y1 - 2011

N2 - We report a single molecule detection scheme to investigate excitation spectra of single emitters at room temperature. We demonstrate the potential of single emitter photoluminescence excitation spectroscopy by recording excitation spectra of single CdSe nanocrystals over a wide spectral range of 100 nm. The spectra exhibit emission intermittency, characteristic of single emitters. We observe large variations in the spectra close to the band edge, which represent the individual heterogeneity of the observed quantum dots. We also find specific excitation wavelengths for which the single quantum dots analyzed show an increased propensity for a transition to a long-lived dark state. We expect that the additional capability of recording excitation spectra at room temperature from single emitters will enable insights into the photophysics of emitters that so far have remained inaccessible.

AB - We report a single molecule detection scheme to investigate excitation spectra of single emitters at room temperature. We demonstrate the potential of single emitter photoluminescence excitation spectroscopy by recording excitation spectra of single CdSe nanocrystals over a wide spectral range of 100 nm. The spectra exhibit emission intermittency, characteristic of single emitters. We observe large variations in the spectra close to the band edge, which represent the individual heterogeneity of the observed quantum dots. We also find specific excitation wavelengths for which the single quantum dots analyzed show an increased propensity for a transition to a long-lived dark state. We expect that the additional capability of recording excitation spectra at room temperature from single emitters will enable insights into the photophysics of emitters that so far have remained inaccessible.

KW - METIS-280828

KW - IR-104424

U2 - 10.3762/bjnano.2.56

DO - 10.3762/bjnano.2.56

M3 - Article

VL - 2

SP - 516

EP - 524

JO - Beilstein journal of nanotechnology

JF - Beilstein journal of nanotechnology

SN - 2190-4286

ER -