Second-order nonlinear optical active calix[4]arene polyimides suitable for frequency doubling in the UV region

Paul J.A. Kenis; Oscar F.J. Noordman; Niek F. van Hulst; Johan F.J. Engbersen; David N. Reinhoudt

doi:10.1021/cm960420g

Second-order nonlinear optical active calix[4]arene polyimides suitable for frequency doubling in the UV region

Paul J.A. Kenis, Oscar F.J. Noordman, Niek F. van Hulst, Johan F.J. Engbersen, David N. Reinhoudt

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Abstract

A new type of soluble calix[4]arene-based polyimides was prepared by reaction of bis(3-aminopropyl) dipropyl functionalized tetranitrocalix[4]arenes with hexafluoroisopropylidene diphthalic anhydride. Spin-coating of these polymers and subsequent electric field poling results in films that are highly transparent above 410 nm and exhibit high and thermally stable second harmonic generation coefficients. These properties make these materials very suitable Ear frequency-doubling applications in the UV region (820-410 nm).

Original language	English
Pages (from-to)	596-601
Journal	Chemistry of materials
Volume	9
Issue number	2
DOIs	https://doi.org/10.1021/cm960420g
Publication status	Published - 1997

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title = "Second-order nonlinear optical active calix[4]arene polyimides suitable for frequency doubling in the UV region",

abstract = "A new type of soluble calix[4]arene-based polyimides was prepared by reaction of bis(3-aminopropyl) dipropyl functionalized tetranitrocalix[4]arenes with hexafluoroisopropylidene diphthalic anhydride. Spin-coating of these polymers and subsequent electric field poling results in films that are highly transparent above 410 nm and exhibit high and thermally stable second harmonic generation coefficients. These properties make these materials very suitable Ear frequency-doubling applications in the UV region (820-410 nm).",

author = "Kenis, {Paul J.A.} and Noordman, {Oscar F.J.} and {van Hulst}, {Niek F.} and Engbersen, {Johan F.J.} and Reinhoudt, {David N.}",

year = "1997",

doi = "10.1021/cm960420g",

language = "English",

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T1 - Second-order nonlinear optical active calix[4]arene polyimides suitable for frequency doubling in the UV region

AU - Kenis, Paul J.A.

AU - Noordman, Oscar F.J.

AU - van Hulst, Niek F.

AU - Engbersen, Johan F.J.

AU - Reinhoudt, David N.

PY - 1997

Y1 - 1997

N2 - A new type of soluble calix[4]arene-based polyimides was prepared by reaction of bis(3-aminopropyl) dipropyl functionalized tetranitrocalix[4]arenes with hexafluoroisopropylidene diphthalic anhydride. Spin-coating of these polymers and subsequent electric field poling results in films that are highly transparent above 410 nm and exhibit high and thermally stable second harmonic generation coefficients. These properties make these materials very suitable Ear frequency-doubling applications in the UV region (820-410 nm).

AB - A new type of soluble calix[4]arene-based polyimides was prepared by reaction of bis(3-aminopropyl) dipropyl functionalized tetranitrocalix[4]arenes with hexafluoroisopropylidene diphthalic anhydride. Spin-coating of these polymers and subsequent electric field poling results in films that are highly transparent above 410 nm and exhibit high and thermally stable second harmonic generation coefficients. These properties make these materials very suitable Ear frequency-doubling applications in the UV region (820-410 nm).

U2 - 10.1021/cm960420g

DO - 10.1021/cm960420g

M3 - Article

SN - 0897-4756

VL - 9

SP - 596

EP - 601

JO - Chemistry of materials

JF - Chemistry of materials

IS - 2

ER -

Second-order nonlinear optical active calix[4]arene polyimides suitable for frequency doubling in the UV region

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