Segmented block copolymers with monodisperse hard segments: the influence of H-bonding on various properties

Gerard J.E. Biemond; Jan Feijen; Reinoud J. Gaymans; Hetty W.M. ten Hoopen

doi:10.1002/mame.200900093

Segmented block copolymers with monodisperse hard segments: the influence of H-bonding on various properties

Gerard J.E. Biemond^*
, Jan Feijen
, Reinoud J. Gaymans
, Hetty W.M. ten Hoopen

^*Corresponding author for this work

Research output: Contribution to journal › Article › Academic › peer-review

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Abstract

The properties of segmented-copolymer-based H-bonding and non-H-bonding crystallisable segments and poly(tetramethylene oxide) segments were studied. The crystallisable segments were monodisperse in length and the non-hydrogen-bonding segments were made of tetraamidepiperazineterephthalamide (TPTPT). The polymers were characterised by DSC, FT-IR, SAXS and DMTA. The mechanical properties were studied by tensile, compression set and tensile set measurements. The TPTPT segmented copolymers displayed low glass transition temperatures (Tg, −70 °C), good low-temperature properties, moderate moduli (G′ ≈ 10–33 MPa) and high melting temperatures (185–220 °C). However, as compared to H-bonded segments, both the modulus and the yield stress were relatively low.

Original language	English
Pages (from-to)	492-501
Journal	Macromolecular materials and engineering
Volume	294
Issue number	8
DOIs	https://doi.org/10.1002/mame.200900093
Publication status	Published - 2009

Keywords

Properties
Block copolymers
Monodisperse
H-bonding
Piperazine
Crystallization

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@article{54f2c2959b5f40eba657ceff9e851ee2,

title = "Segmented block copolymers with monodisperse hard segments: the influence of H-bonding on various properties",

abstract = "The properties of segmented-copolymer-based H-bonding and non-H-bonding crystallisable segments and poly(tetramethylene oxide) segments were studied. The crystallisable segments were monodisperse in length and the non-hydrogen-bonding segments were made of tetraamidepiperazineterephthalamide (TPTPT). The polymers were characterised by DSC, FT-IR, SAXS and DMTA. The mechanical properties were studied by tensile, compression set and tensile set measurements. The TPTPT segmented copolymers displayed low glass transition temperatures (Tg, −70 °C), good low-temperature properties, moderate moduli (G′ ≈ 10–33 MPa) and high melting temperatures (185–220 °C). However, as compared to H-bonded segments, both the modulus and the yield stress were relatively low.",

keywords = "Properties, Block copolymers, Monodisperse, H-bonding, Piperazine, Crystallization",

author = "Biemond, \{Gerard J.E.\} and Jan Feijen and Gaymans, \{Reinoud J.\} and \{ten Hoopen\}, \{Hetty W.M.\}",

note = "AFM analysis by H.W.M. ten Hoopen; AFM shot was published on cover vol. 294 ",

year = "2009",

doi = "10.1002/mame.200900093",

language = "English",

volume = "294",

pages = "492--501",

journal = "Macromolecular materials and engineering",

issn = "1438-7492",

publisher = "Wiley-VCH Verlag",

number = "8",

}

TY - JOUR

T1 - Segmented block copolymers with monodisperse hard segments

T2 - the influence of H-bonding on various properties

AU - Biemond, Gerard J.E.

AU - Feijen, Jan

AU - Gaymans, Reinoud J.

AU - ten Hoopen, Hetty W.M.

N1 - AFM analysis by H.W.M. ten Hoopen; AFM shot was published on cover vol. 294

PY - 2009

Y1 - 2009

N2 - The properties of segmented-copolymer-based H-bonding and non-H-bonding crystallisable segments and poly(tetramethylene oxide) segments were studied. The crystallisable segments were monodisperse in length and the non-hydrogen-bonding segments were made of tetraamidepiperazineterephthalamide (TPTPT). The polymers were characterised by DSC, FT-IR, SAXS and DMTA. The mechanical properties were studied by tensile, compression set and tensile set measurements. The TPTPT segmented copolymers displayed low glass transition temperatures (Tg, −70 °C), good low-temperature properties, moderate moduli (G′ ≈ 10–33 MPa) and high melting temperatures (185–220 °C). However, as compared to H-bonded segments, both the modulus and the yield stress were relatively low.

AB - The properties of segmented-copolymer-based H-bonding and non-H-bonding crystallisable segments and poly(tetramethylene oxide) segments were studied. The crystallisable segments were monodisperse in length and the non-hydrogen-bonding segments were made of tetraamidepiperazineterephthalamide (TPTPT). The polymers were characterised by DSC, FT-IR, SAXS and DMTA. The mechanical properties were studied by tensile, compression set and tensile set measurements. The TPTPT segmented copolymers displayed low glass transition temperatures (Tg, −70 °C), good low-temperature properties, moderate moduli (G′ ≈ 10–33 MPa) and high melting temperatures (185–220 °C). However, as compared to H-bonded segments, both the modulus and the yield stress were relatively low.

KW - Properties

KW - Block copolymers

KW - Monodisperse

KW - H-bonding

KW - Piperazine

KW - Crystallization

U2 - 10.1002/mame.200900093

DO - 10.1002/mame.200900093

M3 - Article

SN - 1438-7492

VL - 294

SP - 492

EP - 501

JO - Macromolecular materials and engineering

JF - Macromolecular materials and engineering

IS - 8

ER -

Segmented block copolymers with monodisperse hard segments: the influence of H-bonding on various properties

Abstract

Keywords

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