Selective catalytic reduction of NOx to N2 over Co-Pt/ZSM-5; Part A. Characterisation and kinetic aspects

S.E. Maisuls; Kulathuiyer Seshan; S. Feast; S. Feast; J.A. Lercher

doi:10.1016/S0926-3373(00)00194-6

Selective catalytic reduction of NOx to N2 over Co-Pt/ZSM-5; Part A. Characterisation and kinetic aspects

S.E. Maisuls, Kulathuiyer Seshan, S. Feast, S. Feast, J.A. Lercher

Research output: Contribution to journal › Article › Academic › peer-review

44 Citations (Scopus)

6 Downloads (Pure)

Abstract

The selective catalytic reduction of NO by propene in the presence of excess oxygen has been studied over catalysts based on Co-Pt supported on ZSM-5. Pure Pt based catalysts are highly active, but produce large amounts of N2O. Bimetallic Co-Pt/ZSM-5 catalysts with low Pt contents (0.1 wt.%) show a synergistic effect by combining high stability and activity of Pt catalysts with the high N2 selectivity of Co catalysts. The lower selectivity to N2O is attributed to its selective conversion over Co. The catalysts also showed high water and sulfur tolerance above 350°C.

Original language	Undefined
Pages (from-to)	69-81
Number of pages	13
Journal	Applied catalysis B: environmental
Volume	29
Issue number	1
DOIs	https://doi.org/10.1016/S0926-3373(00)00194-6
Publication status	Published - 2001

Keywords

METIS-205572
Platinum
Selective catalytic reduction
Nitrogen oxides
ZSM-5
Hydrocarbon
Cobalt
Bimetallic
IR-74472

Access to Document

10.1016/S0926-3373(00)00194-6

Cite this

@article{369ca9dec747406ba490ba9f826f9d13,

title = "Selective catalytic reduction of NOx to N2 over Co-Pt/ZSM-5; Part A. Characterisation and kinetic aspects",

abstract = "The selective catalytic reduction of NO by propene in the presence of excess oxygen has been studied over catalysts based on Co-Pt supported on ZSM-5. Pure Pt based catalysts are highly active, but produce large amounts of N2O. Bimetallic Co-Pt/ZSM-5 catalysts with low Pt contents (0.1 wt.%) show a synergistic effect by combining high stability and activity of Pt catalysts with the high N2 selectivity of Co catalysts. The lower selectivity to N2O is attributed to its selective conversion over Co. The catalysts also showed high water and sulfur tolerance above 350°C.",

keywords = "METIS-205572, Platinum, Selective catalytic reduction, Nitrogen oxides, ZSM-5, Hydrocarbon, Cobalt, Bimetallic, IR-74472",

author = "S.E. Maisuls and Kulathuiyer Seshan and S. Feast and S. Feast and J.A. Lercher",

year = "2001",

doi = "10.1016/S0926-3373(00)00194-6",

language = "Undefined",

volume = "29",

pages = "69--81",

journal = "Applied catalysis B: environmental",

issn = "0926-3373",

publisher = "Elsevier B.V.",

number = "1",

}

TY - JOUR

T1 - Selective catalytic reduction of NOx to N2 over Co-Pt/ZSM-5; Part A. Characterisation and kinetic aspects

AU - Maisuls, S.E.

AU - Seshan, Kulathuiyer

AU - Feast, S.

AU - Lercher, J.A.

PY - 2001

Y1 - 2001

N2 - The selective catalytic reduction of NO by propene in the presence of excess oxygen has been studied over catalysts based on Co-Pt supported on ZSM-5. Pure Pt based catalysts are highly active, but produce large amounts of N2O. Bimetallic Co-Pt/ZSM-5 catalysts with low Pt contents (0.1 wt.%) show a synergistic effect by combining high stability and activity of Pt catalysts with the high N2 selectivity of Co catalysts. The lower selectivity to N2O is attributed to its selective conversion over Co. The catalysts also showed high water and sulfur tolerance above 350°C.

AB - The selective catalytic reduction of NO by propene in the presence of excess oxygen has been studied over catalysts based on Co-Pt supported on ZSM-5. Pure Pt based catalysts are highly active, but produce large amounts of N2O. Bimetallic Co-Pt/ZSM-5 catalysts with low Pt contents (0.1 wt.%) show a synergistic effect by combining high stability and activity of Pt catalysts with the high N2 selectivity of Co catalysts. The lower selectivity to N2O is attributed to its selective conversion over Co. The catalysts also showed high water and sulfur tolerance above 350°C.

KW - METIS-205572

KW - Platinum

KW - Selective catalytic reduction

KW - Nitrogen oxides

KW - ZSM-5

KW - Hydrocarbon

KW - Cobalt

KW - Bimetallic

KW - IR-74472

U2 - 10.1016/S0926-3373(00)00194-6

DO - 10.1016/S0926-3373(00)00194-6

M3 - Article

SN - 0926-3373

VL - 29

SP - 69

EP - 81

JO - Applied catalysis B: environmental

JF - Applied catalysis B: environmental

IS - 1

ER -