Self-assembled monolayers of a multifunctional organic radical

Núria Crivillers; Marta Mas-Torrent; Sandrine Perruchas; Nans Roques; José Vidal-Gancedo; Jaume Veciana; Concepció Rovira; M.L. Basabe Desmonts; B.J. Ravoo; Mercedes Crego Calama; David Reinhoudt

doi:10.1002/anie.200603599

Self-assembled monolayers of a multifunctional organic radical

Núria Crivillers, Marta Mas-Torrent, Sandrine Perruchas, Nans Roques, José Vidal-Gancedo, Jaume Veciana, Concepció Rovira, M.L. Basabe Desmonts, B.J. Ravoo, Mercedes Crego Calama, David Reinhoudt

Research output: Contribution to journal › Article › Academic › peer-review

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Abstract

A radical switch: Covalent and noncovalent interactions have been used to functionalize silicon oxide surfaces with polychlorotriphenylmethyl radicals, which are electroactive and can be reversibly reduced or oxidized to nonmagnetic and nonfluorescent species. Thus, the self-assembled monolayers behave as chemical switches that combine electronic absorption, fluorescence emission, and magnetic outputs.

Original language	Undefined
Pages (from-to)	2215-2219
Number of pages	5
Journal	Angewandte Chemie, International Edition in English
Volume	46
Issue number	13
DOIs	https://doi.org/10.1002/anie.200603599
Publication status	Published - 2007

Keywords

radicals
Molecular devices
Monolayers
IR-72259
Surface chemistry
METIS-241415
Self-Assembly

Access to Document

10.1002/anie.200603599

Cite this

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abstract = "A radical switch: Covalent and noncovalent interactions have been used to functionalize silicon oxide surfaces with polychlorotriphenylmethyl radicals, which are electroactive and can be reversibly reduced or oxidized to nonmagnetic and nonfluorescent species. Thus, the self-assembled monolayers behave as chemical switches that combine electronic absorption, fluorescence emission, and magnetic outputs.",

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T1 - Self-assembled monolayers of a multifunctional organic radical

AU - Crivillers, Núria

AU - Mas-Torrent, Marta

AU - Perruchas, Sandrine

AU - Roques, Nans

AU - Vidal-Gancedo, José

AU - Veciana, Jaume

AU - Rovira, Concepció

AU - Basabe Desmonts, M.L.

AU - Ravoo, B.J.

AU - Crego Calama, Mercedes

AU - Reinhoudt, David

PY - 2007

Y1 - 2007

N2 - A radical switch: Covalent and noncovalent interactions have been used to functionalize silicon oxide surfaces with polychlorotriphenylmethyl radicals, which are electroactive and can be reversibly reduced or oxidized to nonmagnetic and nonfluorescent species. Thus, the self-assembled monolayers behave as chemical switches that combine electronic absorption, fluorescence emission, and magnetic outputs.

AB - A radical switch: Covalent and noncovalent interactions have been used to functionalize silicon oxide surfaces with polychlorotriphenylmethyl radicals, which are electroactive and can be reversibly reduced or oxidized to nonmagnetic and nonfluorescent species. Thus, the self-assembled monolayers behave as chemical switches that combine electronic absorption, fluorescence emission, and magnetic outputs.

KW - radicals

KW - Molecular devices

KW - Monolayers

KW - IR-72259

KW - Surface chemistry

KW - METIS-241415

KW - Self-Assembly

U2 - 10.1002/anie.200603599

DO - 10.1002/anie.200603599

M3 - Article

SN - 0570-0833

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SP - 2215

EP - 2219

JO - Angewandte Chemie, International Edition in English

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