Self-Assembled Monolayers on Gold of β-Cyclodextrin Adsorbates with Different Anchoring Groups

Alejandro Méndez-Ardoy; Tom Steentjes; Tibor Kudernac; Jurriaan Huskens

doi:10.1021/la500172a

Self-Assembled Monolayers on Gold of β-Cyclodextrin Adsorbates with Different Anchoring Groups

Alejandro Méndez-Ardoy, Tom Steentjes, Tibor Kudernac, Jurriaan Huskens

Research output: Contribution to journal › Article › Academic › peer-review

22 Citations (Scopus)

59 Downloads (Pure)

Abstract

We designed multivalent β-cyclodextrin-based adsorbates bearing different anchoring groups aiming to yield stable monolayers with improved packing and close contact of the cavity to the gold surface. Toward this end the primary rim of the β-cyclodextrin was decorated with several functional groups, namely iodide, nitrile, amine, isothiocyanate, methyl sulfide, and isocyanide. Monolayers formed by these adsorbates were characterized by contact angle measurements, surface plasmon resonance spectroscopy, polarization modulation infrared reflection adsorption spectroscopy, X-ray photoelectron spectroscopy, and electrochemistry. The nature of the anchoring group influenced the adsorption kinetics, thickness, layer stability, number of anchoring groups bounded to the surface, and packing in the resulting monolayers. Therefore, chemical manipulation of multivalent adsorbates can be used to modify the properties of their monolayers.

Original language	English
Pages (from-to)	3467-3476
Journal	Langmuir
Volume	30
Issue number	12
DOIs	https://doi.org/10.1021/la500172a
Publication status	Published - 2014

Keywords

2023 OA procedure

Access to Document

10.1021/la500172a

ArticleFinal published version, 1.94 MBLicence: Taverne

Cite this

@article{1481937d57f34e719af533cb64ae5db4,

title = "Self-Assembled Monolayers on Gold of β-Cyclodextrin Adsorbates with Different Anchoring Groups",

abstract = "We designed multivalent β-cyclodextrin-based adsorbates bearing different anchoring groups aiming to yield stable monolayers with improved packing and close contact of the cavity to the gold surface. Toward this end the primary rim of the β-cyclodextrin was decorated with several functional groups, namely iodide, nitrile, amine, isothiocyanate, methyl sulfide, and isocyanide. Monolayers formed by these adsorbates were characterized by contact angle measurements, surface plasmon resonance spectroscopy, polarization modulation infrared reflection adsorption spectroscopy, X-ray photoelectron spectroscopy, and electrochemistry. The nature of the anchoring group influenced the adsorption kinetics, thickness, layer stability, number of anchoring groups bounded to the surface, and packing in the resulting monolayers. Therefore, chemical manipulation of multivalent adsorbates can be used to modify the properties of their monolayers.",

keywords = "2023 OA procedure",

author = "Alejandro M{\'e}ndez-Ardoy and Tom Steentjes and Tibor Kudernac and Jurriaan Huskens",

year = "2014",

doi = "10.1021/la500172a",

language = "English",

volume = "30",

pages = "3467--3476",

journal = "Langmuir",

issn = "0743-7463",

publisher = "American Chemical Society",

number = "12",

}

TY - JOUR

T1 - Self-Assembled Monolayers on Gold of β-Cyclodextrin Adsorbates with Different Anchoring Groups

AU - Méndez-Ardoy, Alejandro

AU - Steentjes, Tom

AU - Kudernac, Tibor

AU - Huskens, Jurriaan

PY - 2014

Y1 - 2014

N2 - We designed multivalent β-cyclodextrin-based adsorbates bearing different anchoring groups aiming to yield stable monolayers with improved packing and close contact of the cavity to the gold surface. Toward this end the primary rim of the β-cyclodextrin was decorated with several functional groups, namely iodide, nitrile, amine, isothiocyanate, methyl sulfide, and isocyanide. Monolayers formed by these adsorbates were characterized by contact angle measurements, surface plasmon resonance spectroscopy, polarization modulation infrared reflection adsorption spectroscopy, X-ray photoelectron spectroscopy, and electrochemistry. The nature of the anchoring group influenced the adsorption kinetics, thickness, layer stability, number of anchoring groups bounded to the surface, and packing in the resulting monolayers. Therefore, chemical manipulation of multivalent adsorbates can be used to modify the properties of their monolayers.

AB - We designed multivalent β-cyclodextrin-based adsorbates bearing different anchoring groups aiming to yield stable monolayers with improved packing and close contact of the cavity to the gold surface. Toward this end the primary rim of the β-cyclodextrin was decorated with several functional groups, namely iodide, nitrile, amine, isothiocyanate, methyl sulfide, and isocyanide. Monolayers formed by these adsorbates were characterized by contact angle measurements, surface plasmon resonance spectroscopy, polarization modulation infrared reflection adsorption spectroscopy, X-ray photoelectron spectroscopy, and electrochemistry. The nature of the anchoring group influenced the adsorption kinetics, thickness, layer stability, number of anchoring groups bounded to the surface, and packing in the resulting monolayers. Therefore, chemical manipulation of multivalent adsorbates can be used to modify the properties of their monolayers.

KW - 2023 OA procedure

U2 - 10.1021/la500172a

DO - 10.1021/la500172a

M3 - Article

SN - 0743-7463

VL - 30

SP - 3467

EP - 3476

JO - Langmuir

JF - Langmuir

IS - 12

ER -

Self-Assembled Monolayers on Gold of β-Cyclodextrin Adsorbates with Different Anchoring Groups

Abstract

Keywords

Access to Document

Fingerprint

Cite this