Self-assembled receptors based on hydrogen bonds

Mattijs Gregor Jurriaan ten Cate

doi:10.3990/1.9789036520539

Self-assembled receptors based on hydrogen bonds

Mattijs Gregor Jurriaan ten Cate

Research output: Thesis › PhD Thesis - Research UT, graduation UT

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Abstract

Self-assembly is nature's favorite, most economic and reliable way to generate large and complex biological systems. Due to the high efficiency of nature using noncovalent interactions to assemble complex aggregates, self-assembly is nowadays considered as one of the most promising ways for building synthetic functional structures. This thesis describes the assembly of large hydrogen-bonded systems (double rosettes) and their ability to act as receptors. Due to the formation of 36 hydrogen bonds that bring together three calix[4]arene dimelamines and six barbiturates or cyanurates, these double rosettes exhibit a high thermodynamic stability.

Original language	English
Qualification	Doctor of Philosophy
Awarding Institution	University of Twente
Supervisors/Advisors	Reinhoudt, David N., Supervisor Crego-Calama, M., Co-Supervisor
Award date	27 May 2004
Place of Publication	Enschede
Publisher	University of Twente
Print ISBNs	978-90-365-2053-9
DOIs	https://doi.org/10.3990/1.9789036520539
Publication status	Published - 27 May 2004

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PhD thesis M.G.J. ten CateFinal published version, 18.6 MB

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title = "Self-assembled receptors based on hydrogen bonds",

abstract = "Self-assembly is nature's favorite, most economic and reliable way to generate large and complex biological systems. Due to the high efficiency of nature using noncovalent interactions to assemble complex aggregates, self-assembly is nowadays considered as one of the most promising ways for building synthetic functional structures. This thesis describes the assembly of large hydrogen-bonded systems (double rosettes) and their ability to act as receptors. Due to the formation of 36 hydrogen bonds that bring together three calix[4]arene dimelamines and six barbiturates or cyanurates, these double rosettes exhibit a high thermodynamic stability.",

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AB - Self-assembly is nature's favorite, most economic and reliable way to generate large and complex biological systems. Due to the high efficiency of nature using noncovalent interactions to assemble complex aggregates, self-assembly is nowadays considered as one of the most promising ways for building synthetic functional structures. This thesis describes the assembly of large hydrogen-bonded systems (double rosettes) and their ability to act as receptors. Due to the formation of 36 hydrogen bonds that bring together three calix[4]arene dimelamines and six barbiturates or cyanurates, these double rosettes exhibit a high thermodynamic stability.

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M3 - PhD Thesis - Research UT, graduation UT

SN - 978-90-365-2053-9

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Self-assembled receptors based on hydrogen bonds

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