Self-assembly and stability of double rosette nanostructures with biological functionalities

M.G.J. ten Cate; Merdan Omerovic; G. Oshovsky; Mercedes Crego Calama; David Reinhoudt

doi:10.1039/b508449k

Self-assembly and stability of double rosette nanostructures with biological functionalities

M.G.J. ten Cate, Merdan Omerovic, G. Oshovsky, Mercedes Crego Calama, David Reinhoudt

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Abstract

The syntheses of calix[4]arene dimelamines that are functionalized with alkyl, aminoalkyl, ureido, pyridyl, carbohydrate, amino acid and peptide functionalities, and their self-assembly with barbituric acid or cyanuric acid derivatives into well-defined hydrogen-bonded nanostructures are described. The thermodynamic stability of these hydrogen-bonded assemblies was studied by CD spectroscopy in mixtures of CHCl3 and MeOH. The stability of the assemblies depends on several steric factors and the polarity of the functional groups connected to the assembly components.

Original language	Undefined
Pages (from-to)	3727-3733
Journal	Organic & biomolecular chemistry
Volume	3
Issue number	20
DOIs	https://doi.org/10.1039/b508449k
Publication status	Published - 2005

Keywords

IR-54688
METIS-229066

Access to Document

10.1039/b508449k

Cite this

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title = "Self-assembly and stability of double rosette nanostructures with biological functionalities",

abstract = "The syntheses of calix[4]arene dimelamines that are functionalized with alkyl, aminoalkyl, ureido, pyridyl, carbohydrate, amino acid and peptide functionalities, and their self-assembly with barbituric acid or cyanuric acid derivatives into well-defined hydrogen-bonded nanostructures are described. The thermodynamic stability of these hydrogen-bonded assemblies was studied by CD spectroscopy in mixtures of CHCl3 and MeOH. The stability of the assemblies depends on several steric factors and the polarity of the functional groups connected to the assembly components.",

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year = "2005",

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AU - ten Cate, M.G.J.

AU - Omerovic, Merdan

AU - Oshovsky, G.

AU - Crego Calama, Mercedes

AU - Reinhoudt, David

PY - 2005

Y1 - 2005

N2 - The syntheses of calix[4]arene dimelamines that are functionalized with alkyl, aminoalkyl, ureido, pyridyl, carbohydrate, amino acid and peptide functionalities, and their self-assembly with barbituric acid or cyanuric acid derivatives into well-defined hydrogen-bonded nanostructures are described. The thermodynamic stability of these hydrogen-bonded assemblies was studied by CD spectroscopy in mixtures of CHCl3 and MeOH. The stability of the assemblies depends on several steric factors and the polarity of the functional groups connected to the assembly components.

AB - The syntheses of calix[4]arene dimelamines that are functionalized with alkyl, aminoalkyl, ureido, pyridyl, carbohydrate, amino acid and peptide functionalities, and their self-assembly with barbituric acid or cyanuric acid derivatives into well-defined hydrogen-bonded nanostructures are described. The thermodynamic stability of these hydrogen-bonded assemblies was studied by CD spectroscopy in mixtures of CHCl3 and MeOH. The stability of the assemblies depends on several steric factors and the polarity of the functional groups connected to the assembly components.

KW - IR-54688

KW - METIS-229066

U2 - 10.1039/b508449k

DO - 10.1039/b508449k

M3 - Article

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