Self-assembly of hyperbranched spheres

W.T.S. Huck; Wilhelm T.S. Huck; F.C.J.M. van Veggel; David Reinhoudt

doi:10.1039/a608577f

Self-assembly of hyperbranched spheres

W.T.S. Huck, Wilhelm T.S. Huck, F.C.J.M. van Veggel, David Reinhoudt

Research output: Contribution to journal › Article › Academic › peer-review

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Abstract

A new type of building block with two coordinatively unsaturated palladium centres has been described that self-assembles in nitromethane solution and disassembles when acetonitrile is added. The resulting hyperbranched, organopalladium spheres have a remarkably narrow size distribution as was evidenced by light-scattering, AFM and TEM measurements. Variation of the structure of the building blocks showed the possibility to vary the size of the self-assembled spheres between 100 and 400 nm.

Original language	Undefined
Pages (from-to)	1213-1219
Journal	Journal of materials chemistry
Volume	7
Issue number	7
DOIs	https://doi.org/10.1039/a608577f
Publication status	Published - 1997

Keywords

METIS-105915
IR-10942

Access to Document

10.1039/a608577f

K10942__

Cite this

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title = "Self-assembly of hyperbranched spheres",

abstract = "A new type of building block with two coordinatively unsaturated palladium centres has been described that self-assembles in nitromethane solution and disassembles when acetonitrile is added. The resulting hyperbranched, organopalladium spheres have a remarkably narrow size distribution as was evidenced by light-scattering, AFM and TEM measurements. Variation of the structure of the building blocks showed the possibility to vary the size of the self-assembled spheres between 100 and 400 nm.",

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journal = "Journal of materials chemistry",

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AU - Huck, W.T.S.

AU - Huck, Wilhelm T.S.

AU - van Veggel, F.C.J.M.

AU - Reinhoudt, David

PY - 1997

Y1 - 1997

N2 - A new type of building block with two coordinatively unsaturated palladium centres has been described that self-assembles in nitromethane solution and disassembles when acetonitrile is added. The resulting hyperbranched, organopalladium spheres have a remarkably narrow size distribution as was evidenced by light-scattering, AFM and TEM measurements. Variation of the structure of the building blocks showed the possibility to vary the size of the self-assembled spheres between 100 and 400 nm.

AB - A new type of building block with two coordinatively unsaturated palladium centres has been described that self-assembles in nitromethane solution and disassembles when acetonitrile is added. The resulting hyperbranched, organopalladium spheres have a remarkably narrow size distribution as was evidenced by light-scattering, AFM and TEM measurements. Variation of the structure of the building blocks showed the possibility to vary the size of the self-assembled spheres between 100 and 400 nm.

KW - METIS-105915

KW - IR-10942

U2 - 10.1039/a608577f

DO - 10.1039/a608577f

M3 - Article

SN - 0959-9428

VL - 7

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JO - Journal of materials chemistry

JF - Journal of materials chemistry

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