Self-organization of gold-containing hydrogen-bonded rosette assemblies on graphite surface

M.S. Vazquez Campos; Socorro Vazquez-Campos; M. Péter; Mingdong Dong; Sailong Xu; Wei Xu; H. Gersen; Trolle R. Linderoth; Holger Schönherr; Flemming Besenbacher; Mercedes Crego Calama; David Reinhoudt

doi:10.1021/la701330v

Self-organization of gold-containing hydrogen-bonded rosette assemblies on graphite surface

M.S. Vazquez Campos, Socorro Vazquez-Campos, M. Péter, Mingdong Dong, Sailong Xu, Wei Xu, H. Gersen, Trolle R. Linderoth, Holger Schönherr, Flemming Besenbacher, Mercedes Crego Calama, David Reinhoudt

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Abstract

The self-organization of supramolecular structures, in particular gold-containing hydrogen-bonded rosettes, on highly oriented pyrolytic graphite (HOPG) surfaces was investigated by tapping-mode atomic force microscopy (TM-AFM) and scanning tunneling microscopy (STM). TM-AFM and high-resolution STM results show that these hydrogen-bonded assemblies self-organize to form highly ordered domains on HOPG surfaces. We find that a subtle change in one of the building blocks induces two different orientations of the assembly with respect to the surface. These results provide information on the control over the construction of supramolecular nanoarchitectures in 2D with the potential for the manufacturing of functional materials based on structural manipulation of molecular components.

Original language	Undefined
Pages (from-to)	10294-10298
Number of pages	5
Journal	Langmuir
Volume	23
Issue number	20
DOIs	https://doi.org/10.1021/la701330v
Publication status	Published - 2007

Keywords

METIS-243308
IR-74699

Access to Document

10.1021/la701330v

Cite this

@article{fc64100bfaca4d808979d7184f8a438d,

title = "Self-organization of gold-containing hydrogen-bonded rosette assemblies on graphite surface",

abstract = "The self-organization of supramolecular structures, in particular gold-containing hydrogen-bonded rosettes, on highly oriented pyrolytic graphite (HOPG) surfaces was investigated by tapping-mode atomic force microscopy (TM-AFM) and scanning tunneling microscopy (STM). TM-AFM and high-resolution STM results show that these hydrogen-bonded assemblies self-organize to form highly ordered domains on HOPG surfaces. We find that a subtle change in one of the building blocks induces two different orientations of the assembly with respect to the surface. These results provide information on the control over the construction of supramolecular nanoarchitectures in 2D with the potential for the manufacturing of functional materials based on structural manipulation of molecular components.",

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year = "2007",

doi = "10.1021/la701330v",

language = "Undefined",

volume = "23",

pages = "10294--10298",

journal = "Langmuir",

issn = "0743-7463",

publisher = "American Chemical Society",

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TY - JOUR

T1 - Self-organization of gold-containing hydrogen-bonded rosette assemblies on graphite surface

AU - Vazquez Campos, M.S.

AU - Vazquez-Campos, Socorro

AU - Péter, M.

AU - Dong, Mingdong

AU - Xu, Sailong

AU - Xu, Wei

AU - Gersen, H.

AU - Linderoth, Trolle R.

AU - Schönherr, Holger

AU - Besenbacher, Flemming

AU - Crego Calama, Mercedes

AU - Reinhoudt, David

PY - 2007

Y1 - 2007

N2 - The self-organization of supramolecular structures, in particular gold-containing hydrogen-bonded rosettes, on highly oriented pyrolytic graphite (HOPG) surfaces was investigated by tapping-mode atomic force microscopy (TM-AFM) and scanning tunneling microscopy (STM). TM-AFM and high-resolution STM results show that these hydrogen-bonded assemblies self-organize to form highly ordered domains on HOPG surfaces. We find that a subtle change in one of the building blocks induces two different orientations of the assembly with respect to the surface. These results provide information on the control over the construction of supramolecular nanoarchitectures in 2D with the potential for the manufacturing of functional materials based on structural manipulation of molecular components.

AB - The self-organization of supramolecular structures, in particular gold-containing hydrogen-bonded rosettes, on highly oriented pyrolytic graphite (HOPG) surfaces was investigated by tapping-mode atomic force microscopy (TM-AFM) and scanning tunneling microscopy (STM). TM-AFM and high-resolution STM results show that these hydrogen-bonded assemblies self-organize to form highly ordered domains on HOPG surfaces. We find that a subtle change in one of the building blocks induces two different orientations of the assembly with respect to the surface. These results provide information on the control over the construction of supramolecular nanoarchitectures in 2D with the potential for the manufacturing of functional materials based on structural manipulation of molecular components.

KW - METIS-243308

KW - IR-74699

U2 - 10.1021/la701330v

DO - 10.1021/la701330v

M3 - Article

SN - 0743-7463

VL - 23

SP - 10294

EP - 10298

JO - Langmuir

JF - Langmuir

IS - 20

ER -