Sieving of Hot Gases by Hyper-Cross-Linked Nanoscale-Hybrid Membranes

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Abstract

Macromolecular networks consisting of homogeneously distributed covalently bonded inorganic and organic precursors are anticipated to show remarkable characteristics, distinct from those of the individual constituents. A novel hypercross-linked ultrathin membrane is presented, consisting of a giant molecular network of alternating polyhedral oligomeric silsesquioxanes and aromatic imide bridges. The hybrid characteristics of the membrane are manifested in excellent gas separation performance at elevated temperatures, providing a new and key enabling technology for many important industrial scale applications.
Original languageEnglish
Pages (from-to)330-335
JournalJournal of the American Chemical Society
Volume136
Issue number1
DOIs
Publication statusPublished - 2014

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Gases
Imides
Membranes
Technology
Temperature

Keywords

  • IR-92663
  • METIS-306446

Cite this

@article{19051d522d7d4232adc9d9c29b9c78a5,
title = "Sieving of Hot Gases by Hyper-Cross-Linked Nanoscale-Hybrid Membranes",
abstract = "Macromolecular networks consisting of homogeneously distributed covalently bonded inorganic and organic precursors are anticipated to show remarkable characteristics, distinct from those of the individual constituents. A novel hypercross-linked ultrathin membrane is presented, consisting of a giant molecular network of alternating polyhedral oligomeric silsesquioxanes and aromatic imide bridges. The hybrid characteristics of the membrane are manifested in excellent gas separation performance at elevated temperatures, providing a new and key enabling technology for many important industrial scale applications.",
keywords = "IR-92663, METIS-306446",
author = "Michiel Raaijmakers and Hempenius, {Mark A.} and Sch{\"o}n, {Peter Manfred} and Vancso, {Gyula J.} and Arian Nijmeijer and Matthias Wessling and Benes, {Nieck Edwin}",
year = "2014",
doi = "10.1021/ja410047u",
language = "English",
volume = "136",
pages = "330--335",
journal = "Journal of the American Chemical Society",
issn = "0002-7863",
publisher = "American Chemical Society",
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}

Sieving of Hot Gases by Hyper-Cross-Linked Nanoscale-Hybrid Membranes. / Raaijmakers, Michiel; Hempenius, Mark A.; Schön, Peter Manfred; Vancso, Gyula J.; Nijmeijer, Arian; Wessling, Matthias; Benes, Nieck Edwin.

In: Journal of the American Chemical Society, Vol. 136, No. 1, 2014, p. 330-335.

Research output: Contribution to journalArticleAcademicpeer-review

TY - JOUR

T1 - Sieving of Hot Gases by Hyper-Cross-Linked Nanoscale-Hybrid Membranes

AU - Raaijmakers, Michiel

AU - Hempenius, Mark A.

AU - Schön, Peter Manfred

AU - Vancso, Gyula J.

AU - Nijmeijer, Arian

AU - Wessling, Matthias

AU - Benes, Nieck Edwin

PY - 2014

Y1 - 2014

N2 - Macromolecular networks consisting of homogeneously distributed covalently bonded inorganic and organic precursors are anticipated to show remarkable characteristics, distinct from those of the individual constituents. A novel hypercross-linked ultrathin membrane is presented, consisting of a giant molecular network of alternating polyhedral oligomeric silsesquioxanes and aromatic imide bridges. The hybrid characteristics of the membrane are manifested in excellent gas separation performance at elevated temperatures, providing a new and key enabling technology for many important industrial scale applications.

AB - Macromolecular networks consisting of homogeneously distributed covalently bonded inorganic and organic precursors are anticipated to show remarkable characteristics, distinct from those of the individual constituents. A novel hypercross-linked ultrathin membrane is presented, consisting of a giant molecular network of alternating polyhedral oligomeric silsesquioxanes and aromatic imide bridges. The hybrid characteristics of the membrane are manifested in excellent gas separation performance at elevated temperatures, providing a new and key enabling technology for many important industrial scale applications.

KW - IR-92663

KW - METIS-306446

U2 - 10.1021/ja410047u

DO - 10.1021/ja410047u

M3 - Article

VL - 136

SP - 330

EP - 335

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

SN - 0002-7863

IS - 1

ER -