Sieving of Hot Gases by Hyper-Cross-Linked Nanoscale-Hybrid Membranes

Michiel Raaijmakers; Mark A. Hempenius; Peter Manfred Schön; Gyula J. Vancso; Arian Nijmeijer; Matthias Wessling; Nieck Edwin Benes

doi:10.1021/ja410047u

Sieving of Hot Gases by Hyper-Cross-Linked Nanoscale-Hybrid Membranes

Michiel Raaijmakers, Mark A. Hempenius, Peter Manfred Schön, Gyula J. Vancso, Arian Nijmeijer, Matthias Wessling, Nieck Edwin Benes

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Abstract

Macromolecular networks consisting of homogeneously distributed covalently bonded inorganic and organic precursors are anticipated to show remarkable characteristics, distinct from those of the individual constituents. A novel hypercross-linked ultrathin membrane is presented, consisting of a giant molecular network of alternating polyhedral oligomeric silsesquioxanes and aromatic imide bridges. The hybrid characteristics of the membrane are manifested in excellent gas separation performance at elevated temperatures, providing a new and key enabling technology for many important industrial scale applications.

Original language	English
Pages (from-to)	330-335
Journal	Journal of the American Chemical Society
Volume	136
Issue number	1
DOIs	https://doi.org/10.1021/ja410047u
Publication status	Published - 2014

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2023 OA procedure

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10.1021/ja410047u

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title = "Sieving of Hot Gases by Hyper-Cross-Linked Nanoscale-Hybrid Membranes",

abstract = "Macromolecular networks consisting of homogeneously distributed covalently bonded inorganic and organic precursors are anticipated to show remarkable characteristics, distinct from those of the individual constituents. A novel hypercross-linked ultrathin membrane is presented, consisting of a giant molecular network of alternating polyhedral oligomeric silsesquioxanes and aromatic imide bridges. The hybrid characteristics of the membrane are manifested in excellent gas separation performance at elevated temperatures, providing a new and key enabling technology for many important industrial scale applications.",

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AU - Schön, Peter Manfred

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AU - Nijmeijer, Arian

AU - Wessling, Matthias

AU - Benes, Nieck Edwin

PY - 2014

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AB - Macromolecular networks consisting of homogeneously distributed covalently bonded inorganic and organic precursors are anticipated to show remarkable characteristics, distinct from those of the individual constituents. A novel hypercross-linked ultrathin membrane is presented, consisting of a giant molecular network of alternating polyhedral oligomeric silsesquioxanes and aromatic imide bridges. The hybrid characteristics of the membrane are manifested in excellent gas separation performance at elevated temperatures, providing a new and key enabling technology for many important industrial scale applications.

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JF - Journal of the American Chemical Society

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Sieving of Hot Gases by Hyper-Cross-Linked Nanoscale-Hybrid Membranes

Abstract

Keywords

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