Abstract
In this study, the influence of the molecular structure of the rubber, the carbon black loading and de-vulcanization time and temperature on the thermo-chemical de-vulcanization efficiency of whole tire rubber was investigated by correlating sol fraction and crosslink density (Horikx-Verbruggen method). Differences in molecular structure influence the de-vulcanization mechanisms of rubbers as well as the efficiency. Increasing carbon black loadings result in higher crosslink densities due to a deactivation of the de-vulcanization aid. Variation of de-vulcanization temperature and time results in different degrees of heat accumulation in the rubber during de-vulcanization and thus leads to different de-vulcanization efficiencies.
Original language | English |
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Pages (from-to) | 1118-1123 |
Number of pages | 6 |
Journal | Journal of Environmental Treatment Techniques |
Volume | 8 |
Issue number | 3 |
Publication status | Published - 20 Sept 2020 |
Keywords
- Carbon black
- De-vulcanization
- Recycling
- Tire rubber