Simulations of elementary processes in entangle wormlike micelles under tension : a kinetic pathway to Y-junctions and shear induced structures

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Abstract

The merging process of two amphiphilic cylindrical micelles has been simulated using a coarse grained model in which amphiphiles are represented as chains of one head particle and four tail particles. In our set-up with twisted boundary conditions, a ring-shaped worm is effectively entangled with itself. Upon stretching the box, putting the worms under tension, a fusion into an H-like structure is observed, which eventually transforms into an almost tensionless structure with two freely gliding Y-junctions. The tensions on the worms never reach the point where scission becomes an alternative to fusion. We end with a short discussion of the possible implications of these observations.
Original languageUndefined
Pages (from-to)S3965-S3974
Number of pages10
JournalJournal of physics: Condensed matter
Volume16
Issue number38
DOIs
Publication statusPublished - 2004

Keywords

  • METIS-218908
  • IR-87004

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