Spreading on viscoelastic solids: Are contact angles selected by Neumann's law?

M. van Gorcum*, S. Karpitschka, B. Andreotti, J.H. Snoeijer

*Corresponding author for this work

Research output: Contribution to journalArticleAcademicpeer-review

34 Citations (Scopus)
72 Downloads (Pure)


The spreading of liquid drops on soft substrates is extremely slow, owing to strong viscoelastic dissipation inside the solid. A detailed understanding of the spreading dynamics has remained elusive, partly owing to the difficulty in quantifying the strong viscoelastic deformations below the contact line that determine the shape of moving wetting ridges. Here we present direct experimental visualisations of the dynamic wetting ridge using shadowgraphic imaging, complemented with measurements of the liquid contact angle. It is observed that the wetting ridge exhibits a rotation that follows exactly the dynamic liquid contact angle-as was previously hypothesized [Karpitschka et al., Nat. Commun., 2015, 6, 7891]. This experimentally proves that, despite the contact line motion, the wetting ridge is still governed by Neumann's law. Furthermore, our experiments suggest that moving contact lines lead to a variable surface tension of the substrate. We therefore set up a new theory that incorporates the influence of surface strain, for the first time including the so-called Shuttleworth effect into the dynamical theory for soft wetting. It includes a detailed analysis of the boundary conditions at the contact line, complemented by a dissipation analysis, which shows, again, the validity of Neumann's balance.

Original languageEnglish
Pages (from-to)1306-1322
Number of pages17
JournalSoft matter
Issue number5
Early online date26 Dec 2019
Publication statusPublished - 7 Feb 2020


  • UT-Hybrid-D
  • 22/2 OA procedure


Dive into the research topics of 'Spreading on viscoelastic solids: Are contact angles selected by Neumann's law?'. Together they form a unique fingerprint.

Cite this