Stability and Applications of Electrochemically-Active Self-Assembled Monolayers

Marcel W.J. Beulen; Frank C.J.M. van Veggel; David Reinhoudt

doi:10.1007/978-94-011-5010-1

Stability and Applications of Electrochemically-Active Self-Assembled Monolayers

Marcel W.J. Beulen, Frank C.J.M. van Veggel, David Reinhoudt

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › Academic › peer-review

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Abstract

The electrochemical stability of monolayers is important for future applications. A potential window for self-assembled monolayers in aqueous inert electrolyte was obtained using Cyclic Voltammetry, Electrochemical Impedance Spectroscopy and Heterogeneous Electron Transfer. Also electrochemical techniques can be used for sensing applications. We investigated mixed monolayers of ferrocenethiol and an acid alkylthiol. Deprotonation of the acid by an alkaline electrolyte influences the other part of the mixed monolayer. The formal potential of ferrocene is shifted about 150 mV cathodically by the negative charge in the carboxylate part of the layer.

Original language	English
Title of host publication	Sensor technology in the Netherlands - state of the art
Subtitle of host publication	proceedings of the Dutch Sensor Conference, 2-3 March, 1998, University of Twente, the Netherlands
Editors	A. van den Berg, P. Bergveld
Place of Publication	Dordrecht
Publisher	Kluwer Academic Publishers
Pages	293-297
ISBN (Electronic)	978-94-011-5010-1
ISBN (Print)	978-94-010-6103-2
DOIs	https://doi.org/10.1007/978-94-011-5010-1
Publication status	Published - 1998
Event	Dutch Sensor Conference 1998: Sensor Technology in the Netherlands: State of the Art - University of Twente, Enschede, Netherlands Duration: 2 Mar 1998 → 3 Mar 1998

Publication series

Name	MESA monographs
Publisher	Kluwer Academic Publishers
Volume	2

Conference

Conference	Dutch Sensor Conference 1998
Country/Territory	Netherlands
City	Enschede
Period	2/03/98 → 3/03/98

Keywords

Monolayers
Electrochemistry

Access to Document

10.1007/978-94-011-5010-1

Cite this

Beulen, M. W. J., van Veggel, F. C. J. M., & Reinhoudt, D. (1998). Stability and Applications of Electrochemically-Active Self-Assembled Monolayers. In A. van den Berg, & P. Bergveld (Eds.), Sensor technology in the Netherlands - state of the art: proceedings of the Dutch Sensor Conference, 2-3 March, 1998, University of Twente, the Netherlands (pp. 293-297). (MESA monographs; Vol. 2). Kluwer Academic Publishers. https://doi.org/10.1007/978-94-011-5010-1

Beulen, Marcel W.J. ; van Veggel, Frank C.J.M. ; Reinhoudt, David. / Stability and Applications of Electrochemically-Active Self-Assembled Monolayers. Sensor technology in the Netherlands - state of the art: proceedings of the Dutch Sensor Conference, 2-3 March, 1998, University of Twente, the Netherlands. editor / A. van den Berg ; P. Bergveld. Dordrecht : Kluwer Academic Publishers, 1998. pp. 293-297 (MESA monographs).

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title = "Stability and Applications of Electrochemically-Active Self-Assembled Monolayers",

abstract = "The electrochemical stability of monolayers is important for future applications. A potential window for self-assembled monolayers in aqueous inert electrolyte was obtained using Cyclic Voltammetry, Electrochemical Impedance Spectroscopy and Heterogeneous Electron Transfer. Also electrochemical techniques can be used for sensing applications. We investigated mixed monolayers of ferrocenethiol and an acid alkylthiol. Deprotonation of the acid by an alkaline electrolyte influences the other part of the mixed monolayer. The formal potential of ferrocene is shifted about 150 mV cathodically by the negative charge in the carboxylate part of the layer.",

keywords = "Monolayers, Electrochemistry",

author = "Beulen, {Marcel W.J.} and {van Veggel}, {Frank C.J.M.} and David Reinhoudt",

year = "1998",

doi = "10.1007/978-94-011-5010-1",

language = "English",

isbn = "978-94-010-6103-2",

series = "MESA monographs",

publisher = "Kluwer Academic Publishers",

pages = "293--297",

editor = "{van den Berg}, A. and P. Bergveld",

booktitle = "Sensor technology in the Netherlands - state of the art",

address = "Netherlands",

note = "Dutch Sensor Conference 1998 : Sensor Technology in the Netherlands: State of the Art ; Conference date: 02-03-1998 Through 03-03-1998",

}

Beulen, MWJ, van Veggel, FCJM & Reinhoudt, D 1998, Stability and Applications of Electrochemically-Active Self-Assembled Monolayers. in A van den Berg & P Bergveld (eds), Sensor technology in the Netherlands - state of the art: proceedings of the Dutch Sensor Conference, 2-3 March, 1998, University of Twente, the Netherlands. MESA monographs, vol. 2, Kluwer Academic Publishers, Dordrecht, pp. 293-297, Dutch Sensor Conference 1998, Enschede, Netherlands, 2/03/98. https://doi.org/10.1007/978-94-011-5010-1

Stability and Applications of Electrochemically-Active Self-Assembled Monolayers. / Beulen, Marcel W.J.; van Veggel, Frank C.J.M.; Reinhoudt, David.
Sensor technology in the Netherlands - state of the art: proceedings of the Dutch Sensor Conference, 2-3 March, 1998, University of Twente, the Netherlands. ed. / A. van den Berg; P. Bergveld. Dordrecht: Kluwer Academic Publishers, 1998. p. 293-297 (MESA monographs; Vol. 2).

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › Academic › peer-review

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AU - Reinhoudt, David

PY - 1998

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N2 - The electrochemical stability of monolayers is important for future applications. A potential window for self-assembled monolayers in aqueous inert electrolyte was obtained using Cyclic Voltammetry, Electrochemical Impedance Spectroscopy and Heterogeneous Electron Transfer. Also electrochemical techniques can be used for sensing applications. We investigated mixed monolayers of ferrocenethiol and an acid alkylthiol. Deprotonation of the acid by an alkaline electrolyte influences the other part of the mixed monolayer. The formal potential of ferrocene is shifted about 150 mV cathodically by the negative charge in the carboxylate part of the layer.

AB - The electrochemical stability of monolayers is important for future applications. A potential window for self-assembled monolayers in aqueous inert electrolyte was obtained using Cyclic Voltammetry, Electrochemical Impedance Spectroscopy and Heterogeneous Electron Transfer. Also electrochemical techniques can be used for sensing applications. We investigated mixed monolayers of ferrocenethiol and an acid alkylthiol. Deprotonation of the acid by an alkaline electrolyte influences the other part of the mixed monolayer. The formal potential of ferrocene is shifted about 150 mV cathodically by the negative charge in the carboxylate part of the layer.

KW - Monolayers

KW - Electrochemistry

U2 - 10.1007/978-94-011-5010-1

DO - 10.1007/978-94-011-5010-1

M3 - Conference contribution

SN - 978-94-010-6103-2

T3 - MESA monographs

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BT - Sensor technology in the Netherlands - state of the art

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Beulen MWJ, van Veggel FCJM, Reinhoudt D. Stability and Applications of Electrochemically-Active Self-Assembled Monolayers. In van den Berg A, Bergveld P, editors, Sensor technology in the Netherlands - state of the art: proceedings of the Dutch Sensor Conference, 2-3 March, 1998, University of Twente, the Netherlands. Dordrecht: Kluwer Academic Publishers. 1998. p. 293-297. (MESA monographs). doi: 10.1007/978-94-011-5010-1

Stability and Applications of Electrochemically-Active Self-Assembled Monolayers

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